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Betweenanenes with Vinylic Heteroatoms. Route to Sulfur Analogues via -Sigmatropic Rearrangement
Nickon, Alex,Rodriguez, Abimael D.,Ganguly, Rathindra,Shirhatti, Vilas
, p. 2767 - 2777 (1985)
The goal was to devise routes to double-domed olefins ("betweenanenes") having a heteroatom connected directly to the double bond.Our approach centered on -sigmatropic rearrangement of ylides, and specifically we sought to learn if dithioketals could
