Betweenanenes with Vinylic Heteroatoms. Route to Sulfur Analogues via -Sigmatropic Rearrangement

DOI: 10.1021/jo00215a035

Source and publish data:

Journal of Organic Chemistry p. 2767 - 2777 (1985)

Update date:2022-08-02

Topics:

Authors:

Nickon, Alex

Rodriguez, Abimael D.

Ganguly, Rathindra

Shirhatti, Vilas

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00215a035

The goal was to devise routes to double-domed olefins ("betweenanenes") having a heteroatom connected directly to the double bond.Our approach centered on <2,3>-sigmatropic rearrangement of ylides, and specifically we sought to learn if dithioketals could

Full text of DOI:10.1021/jo00215a035

Products guided by the article

Product name:2-<(phenylseleno)methyl>cyclododecanone

Cas No:96555-23-6

R&D Labs maybe for 96555-23-6

Chengdu Push Bio-technology Co., Ltd

Contact:86-28-85370565

Address:No.8 Wuke West Second Road, Wuhou
Shandong General Materials Co.,Ltd（Shandong Aoertong Chemical Co., Ltd）

Contact:86-531-88072280

Address:No. 1825 Hualong Road, Licheng District, Jinan, Shandong, China
Nantong LiKai Chemical Co.,Ltd

Contact:+86-513-89068669

Address:Jincheng Science Park
Jiangsu Zhenfang Chemical CO.,LTD.(Suzhou Zhenfang Chemical Factory)

Contact:+86-512-69598882

Address:Room1201, Jiayuan Road No.1018, Xiangcheng District, Suzhou, China
Nanjing Habo Medical Technology Co., Ltd.

Contact:025－85769882

Address:No.108. Ganjiabian east. Qixia District .Nanjing

Relevant to this article

Development of an improved rhodium catalyst for z-selective anti-markovnikov addition of carboxylic acids to terminal alkynes

Doi:10.1002/chem.201300160
(2013)
Synthesis and biological evaluation of novel β-carbolines as potent cytotoxic and DNA intercalating agents

Doi:10.1248/cpb.58.901
(2010)
Catechol-O-methyltransferase-inhibiting pyrocatechol derivatives: Synthesis and structure-activity studies

Doi:10.1002/hlca.19890720511
(1989)
Design, synthesis and biological evaluation of novel isoindolinone derivatives as potent histone deacetylase inhibitors

Doi:10.1016/j.ejmech.2019.02.032
(2019)
A highly selective structure-based virtual screening model of Palm i allosteric inhibitors of HCV Ns5b polymerase enzyme and its application in the discovery and optimization of new analogues

Doi:10.1016/j.ejmech.2012.04.016
(2012)
ON THE GENERATION OF STABILIZED LOW-VALENT METALLOCENE DERIVATIVES. THE DIRECT SYNTHESIS AND REDUCTIVE COUPLING REACTIONS OF 1-METHYLTHIOALKYNE-ZIRCONOCENE COMPLEXES

Doi:10.1016/S0040-4039(00)99422-X
(1989)

Article Doi