Betweenanenes with Vinylic Heteroatoms. Route to Sulfur Analogues via -Sigmatropic Rearrangement

DOI: 10.1021/jo00215a035

Source and publish data:

Journal of Organic Chemistry p. 2767 - 2777 (1985)

Update date:2022-08-02

Topics:

Authors:

Nickon, Alex

Rodriguez, Abimael D.

Ganguly, Rathindra

Shirhatti, Vilas

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Article abstract of DOI:10.1021/jo00215a035

The goal was to devise routes to double-domed olefins ("betweenanenes") having a heteroatom connected directly to the double bond.Our approach centered on <2,3>-sigmatropic rearrangement of ylides, and specifically we sought to learn if dithioketals could

Full text of DOI:10.1021/jo00215a035

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