93390-76-2Relevant articles and documents
DITHIOKETALS AS PRECURSORS FOR SIGMATROPIC REARRANGEMENTS. SYNTHESIS OF BETWEENANENES WITH VINYLIC HETEROATOMS.
Nickon, Alex,Rodriguez, Abimael,Shirhatti, Villas,Ganguly, Rothin
, p. 3555 - 3558 (1984)
Alkoxycarbonyl-stabilized ylides from gem-disulfides undergo sigmatropic shifts and provided the first entry to betweenanenes with a heteroatom (sulfur) directly attached to the encapsulated olefinic carbon
Betweenanenes with Vinylic Heteroatoms. Route to Sulfur Analogues via -Sigmatropic Rearrangement
Nickon, Alex,Rodriguez, Abimael D.,Ganguly, Rathindra,Shirhatti, Vilas
, p. 2767 - 2777 (2007/10/02)
The goal was to devise routes to double-domed olefins ("betweenanenes") having a heteroatom connected directly to the double bond.Our approach centered on -sigmatropic rearrangement of ylides, and specifically we sought to learn if dithioketals could