96689-74-6

Basic information

• Product Name: 2-(2-allylphenyl)-1,3-dioxolane
• Synonyms: 2-(2-allylphenyl)-1,3-dioxolane
• CAS NO: 96689-74-6
• Molecular Formula: C₁₂H₁₄O₂
• Molecular Weight: 190.23836
• Mol File: 96689-74-6.mol
• Article Data: 10

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-(2-allylphenyl)-1,3-dioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-allylphenyl)-1,3-dioxolane(96689-74-6)
• EPA Substance Registry System: 2-(2-allylphenyl)-1,3-dioxolane(96689-74-6)

Safety Data

• Hazardous Substances Data: 96689-74-6(Hazardous Substances Data)

Usage

Chemical Family

2-(2-allylphenyl)-1,3-dioxolane belongs to the family of dioxolanes, which are cyclic organic compounds containing a 1,3-dioxolane skeleton.

Physical Properties

It is a clear, colorless liquid with a molecular formula of C11H14O2 and a molecular weight of 178.23 g/mol.

Usage

It is commonly used as a fragrance ingredient in various consumer products, such as perfumes, soaps, and cosmetics, due to its floral and sweet aroma.

Safety Concerns

It has been identified as a potential allergen and skin irritant, so caution should be exercised when handling products containing this compound.

Potential Applications

2-(2-allylphenyl)-1,3-dioxolane has been evaluated for its potential use as a pharmaceutical intermediate and in organic synthesis.

Upstream product

• 34824-58-3 2-(2-bromophenyl)-1,3-dioxolan 
• 591-87-7 Allyl acetate 
• 40138-16-7 2-formylbenzene boronic acid 
• 62708-42-3 o-allylbenzaldehyde 
• 107-21-1 ethylene glycol 
• 7366-47-4 2-(2'-chlorophenyl)-1,3-dioxolane 
• 762-72-1 allyl-trimethyl-silane 
• 6630-33-7 ortho-bromobenzaldehyde 
• 106-95-6 allyl bromide 

Downstream Products

• 1245795-96-3 2-(2-((2,2-dibromocyclopropyl)methyl)phenyl)-1,3-dioxolane 
• 1374967-23-3 C₂₃H₂₂N₂O₃ 
• 62708-42-3 o-allylbenzaldehyde 

Relevant articles and documents

NHC-catalyzed oxidative cyclization reaction for the synthesis of 3-substituted phthalides

An efficient NHC-catalyzed domino oxidation/oxa-Michael addition reaction of 2-alkenylbenzaldehydes has been developed to afford 3-substituted phthalides bearing a C3-stereogenic center with a broad substrate scope and wide functional group tolerance. The preliminary results of the asymmetric process have been provided as well. the Partner Organisations 2014.

Expanding the regioselective enzymatic repertoire: Oxidative mono-cleavage of dialkenes catalyzed by Trametes hirsuta

The first report of a biocatalytic regioselective oxidative mono-cleavage of dialkenes was successfully achieved employing a cell-free enzyme preparation from Trametes hirsuta at the expense of molecular oxygen. Selected reactions were performed on a preparative scale affording high to excellent conversions and chemoselectivities. The Royal Society of Chemistry 2012.

Practical iron-catalyzed allylations of aryl grignard reagents

An operationally simple iron-catalyzed reductive cross-coupling reaction between aryl halides and allyl electrophiles has been developed. The underlying domino process exhibits high versatility with respect to the allylic leaving group (acetate, tosylate, diethyl phosphate, methyl carbonate, trimethylsilanolate, methanethiolate, chloride, bromide) and high economic and environmental sustainability with respect to the catalyst system (0.2-5 mol% tris(acetylacetonato)iron(III), ligand-free) and reaction conditions (tetrahydrofuran, 0°C, 45 min).