96746-02-0Relevant articles and documents
Synthesis of α-Oxo Sulfines from Enol Silyl Ethers and Thionyl Chloride
Lenz, Bodo G.,Regeling, Hendrik,Rozendaal, Hendrik L. M. van,Zwanenburg, Binne
, p. 2930 - 2934 (1985)
The reaction of some α-methylene ketones 1 with thionyl chloride leads to α-oxo sulfines 3 provided the ketone is sufficiently enolized.The reaction of trimethylsilyl enol ethers 2 is a more efficient and versatile method for the synthesis of α-oxo sulfin