Synthesis of α-Oxo Sulfines from Enol Silyl Ethers and Thionyl Chloride

DOI: 10.1021/jo00216a024

Source and publish data:

Journal of Organic Chemistry p. 2930 - 2934 (1985)

Update date:2022-08-04

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Authors:

Lenz, Bodo G.

Regeling, Hendrik

Rozendaal, Hendrik L. M. van

Zwanenburg, Binne

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Article abstract of DOI:10.1021/jo00216a024

The reaction of some α-methylene ketones 1 with thionyl chloride leads to α-oxo sulfines 3 provided the ketone is sufficiently enolized.The reaction of trimethylsilyl enol ethers 2 is a more efficient and versatile method for the synthesis of α-oxo sulfin

Full text of DOI:10.1021/jo00216a024

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