96856-58-5Relevant academic research and scientific papers
Cyclization by intramolecular carbolithiation of alkyl- and vinyllithiums prepared by reductive lithiation: Surprising stereochemistry in the lithium oxyanion accelerated cyclization
Deng, Kai,Bensari, Ahlem,Cohen, Theodore
, p. 12106 - 12107 (2007/10/03)
The versatility of intramolecular carbolithiation of simple alkenes to yield cyclopentylmethyllithiums by unconjugated organolithiums is greatly increased (1) by generating the organolithiums by reductive lithiation of phenyl thioethers with aromatic radi
A General Preparative Method for Carbonyl-Protected γ-Lithioketones via Reductive Lithiation. Synthetic Uses of the Bishomoenolate Equivalents
Cohen, Theodore,Zhang, Birong,Cherkauskas, John P.
, p. 11569 - 11584 (2007/10/02)
The mixed cuprates, generated by reductive lithiation of bis(phenylthio)acetals using lithium 4,4'-di-tert-butylbiphenylide (LDBB), followed by addition of cuprous bromide-dimethyl sulfide complex, undergo conjugate addition to enones in the presence of t
