97073-73-9Relevant academic research and scientific papers
Synthesis and structure of the first cobalt(I)-siloxide complex
Kownacki, Ireneusz,Kubicki, Maciej,Marciniec, Bogdan
, p. 3015 - 3018 (2001)
Synthesis, spectroscopic (1H NMR, IR) characterisation and X-ray structure of the first cobalt(I)-siloxide complex, [Co(PPh3)3(OSiMe3)] (I), have been presented. Complex I is synthesised by the reaction of [CoCl(PPh3)3] with trimethylsilanolate. The complex occupies a special position of the space group P3? on the three-fold axis passing through the Co, O and Si atoms. The coordination of cobalt is tetrahedral.
