97106-63-3Relevant academic research and scientific papers
Ortho-Trialkylstannyl Arylphosphanes by C-P and C-Sn Bond Formation in Arynes
Li, Yuanming,Chakrabarty, Shyamal,Mück-Lichtenfeld, Christian,Studer, Armido
supporting information, p. 802 - 806 (2016/02/27)
A novel and efficient approach to ortho-trialkylstannyl arylphosphanes by the reaction of arynes generated in situ with stannylated phosphanes (R3Sn-PR2) is described. Concurrent C-P and C-Sn bond formation occurs with high yields, and stannylated products are easily transformed into valuable ortho-substituted arylphosphanes. The reaction features high efficiency, good regioselectivity, and excellent practicality.
