97194-51-9Relevant academic research and scientific papers
Reactions of benzyl methyl substituted-benzyl phosphites with tert- butyl hypochlorite: 'Balanced TS' validating reactivity/selectivity principle
Kim, Sung Soo,Zhu, Yu,Oh, In Seok,Lim, Chang Gyeong
, p. 836 - 842 (2007/10/03)
Reactions of a series of several benzyl methyl substituted-benzyl phosphites with tert-butyl hypochlorite were investigated. The reactions produced phosphates, isobutene, alkyl chlorides, and benzyl chlorides via phosphonium chlorides as intermediates. Fu
A NEW, CONVENIENT AND EFFICIENT GENERAL PROCEDURE FOR THE CONVERSION OF ALCOHOLS INTO THEIR DIBENZYL PHOSPHOROTRIESTERS USING N,N-DIETHYL DIBENZYL PHOSPHORAMIDITE
Perich, J. W.,Johns, R. B.
, p. 101 - 102 (2007/10/02)
A general procedure is described for the near-quantitative preparation of alkyl dibenzyl phosphates by treating primary, secondary or tertiary alcohols with N,N-diethyl dibenzyl phosphoramidite/1H,5-methyltetrazole followed by mild oxidation of the resultant alkyl dibenzyl phosphites with 3-chloroperoxybenzoic acid.
