97286-53-8

Upstream product

• 22172-30-1 dibromotetracarbonylmolybdenum(II) 
• 97222-10-1 sodium-2,6-diphenylthiophenolate 
• 15712-13-7 dichlorotetracarbonylmolybdenum 

Downstream Products

• 134026-46-3 {Mo(dpt)2(CO)2(phen)} 
• 102913-78-0 {Mo((C₆H₅)2(C₆H₃S))2(CO)(P(C₆H₅)2(CH₂)2P(C₆H₅)2)} 
• 134108-00-2 bis(2,6-diphenylbenzenethiolato)bipyridylbiscarbonylmolybdenum(II) 
• 102913-78-0 {Mo((C₆H₅)2C₆H₃S)2(CO)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)} 

Relevant academic research and scientific papers

A Monomeric Molybdenum Thiolato-complex with a Chelated η6-Arene Ligand. The Preparation and Structure of 6-Ph)PhC6H3S-2,6>(SC6H3Ph2-2,6)(CO)>

Sodium 2,6-diphenylbenzenethiolate reacts with to give the chelated η6-arene complex 6-Ph)PhC6H3S-2,6>(SC6H3Ph2-2,6)(CO)> (1) in good yield, the X-ray crystal structure of which reveals a distored 'piano-stool' geometry.

Co-ordination Chemistry of 2,6-Diphenylthiophenol. The Synthesis and X-Ray Crystal Structures of Some Molybdenum and Rhodium Complexes with ?- or η6-Phenyl-Metal Interactions

Reaction of with the 2,6-diphenylthiophenolate anion (dpt) gives the complex 6-dpt)(dpt)(CO)>, with one thiol phenyl substitutent η6-bonded to the molybdenum.Crystal data: space group P21/c with a = 13.939(3), b = 10.548(3) c = 20.863(5) Angstroem, β = 106.88(1) deg and Z = 4.The η6-arene ligand is labile and is reversibly replaced by CO.Replacement of this ligand also occurs with 2,2'-bipyridyl(bipy), 1,10-phenanthroline (phen), and 1,2-bis(diphenylphosphino)ethane (dppe) to give the dicarbonyl complexes (L = bipy or phen) or the monocarbonyl complex .The X-ray crystal structure of the bipy derivative and the mechanism of its formation is discussed.Crystal data: space group P21/c with a = 10.567(3), b = 22.843(5), c = 18.341(3) Angstroem, β = 105.2(2) deg and Z = 4.Reaction of RhCl3 with dpt gave the dinuclear species .An X-ray crystal structure reveals that each bridging thiolate ligand is also ?-bonded to rhodium via one of the phenyl carbons of the thiolate substitutents.Crystal data: space group P21/n, a = 11.991(2), b = 20.426(4), c = 15.910(4) Angstreom, β = 90.42(1) and Z = 2.