A Monomeric Molybdenum Thiolato-complex with a Chelated η6-Arene Ligand. The Preparation and Structure of 6-Ph)PhC6H3S-2,6>(SC6H3Ph2-2,6)(CO)>

DOI: 10.1039/c39850000257

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 257 - 259 (1985)

Update date:2022-08-04

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Authors:

Bishop, Peter T.

Dilworth, Jonathan R.

Zubieta, Jon A.

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Article abstract of DOI:10.1039/c39850000257

Sodium 2,6-diphenylbenzenethiolate reacts with to give the chelated η⁶-arene complex 6-Ph)PhC6H3S-2,6>(SC6H3Ph2-2,6)(CO)> (1) in good yield, the X-ray crystal structure of which reveals a distored 'piano-stool' geometry.

Full text of DOI:10.1039/c39850000257

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