973-18-2

Upstream product

• 827-15-6 1,2,3,4,5-pentafluoro-6-iodobenzene 
• 18064-78-3 bis(pentafluorophenyl)diselane 
• 40586-73-0 pentafluorobenzeneselenenyl chloride 
• 1076-44-4 pentafluorophenyl lithium 
• 30123-12-7 silver(I)pentafluorobenzene 
• 122183-95-3 C₁₂F₁₂Se 
• 7782-49-2 selenium 
• 941-78-6 pentafluorophenylmercury chloride 
• 10025-68-0 diselenium dichloride 
• 462-06-6 fluorobenzene 
• 7783-70-2 antimony pentafluoride 
• 363-72-4 Pentafluorobenzene 
• 10026-03-6 selenium tetrachloride 
• 879-05-0 2,3,4,5,6-pentafluorophenylmagnesium bromide 

Downstream Products

• 122183-95-3 C₁₂F₁₂Se 
• 1043-50-1 pentafluorophenyl sulfide 
• 434-90-2 decafluorobiphenyl 
• 18707-14-7 bis(pentafluorophenyl) sulphone 
• 967-95-3 1,1′-sulfanediylbis(2,3,5,6-tetrafluorobenzene) 

Relevant academic research and scientific papers

Catalysis with Pnictogen, Chalcogen, and Halogen Bonds

Halogen- and chalcogen-based σ-hole interactions have recently received increased interest in non-covalent organocatalysis. However, the closely related pnictogen bonds have been neglected. In this study, we introduce conceptually simple, neutral, and mon

New aspects in the chemistry of aromatic and fluoroaromatic selenium and tellurium compounds: Similarities and diversities

Polyfluorinated aromatic selenium and tellurium compounds are synthesized and their chemistry and properties discussed. Besides the standard characterization by spectroscopic methods, several crystal structures were obtained. Improved syntheses for the st

Oxidative perfluoroorganylation methods in group 12-16 chemistry: The reactions of haloperfluoroorganics and In and InBr, a convenient new route to AgRf (Rf = CF3, C6F5) and reactions of AgRf

Perfluoroiodo organics RfI (Rf = n-CnF2n+1 (n = 1, 2, 3, 4, 6), i-C3F7, C6F5) and C6F5Br react with elemental indium in polyethers or THF to give

Synthesis, chemistry, and characterization of perfluoroaromatic selenium derivatives

The reaction of perfluoroaryllithium RC6F4Li, where R = F or 4- CF3C6F4O, respectively, with selenium gives the known diselanes (RC6F4Se)2 (1a, 1b). Redox reactions of

POSSIBILITY OF USING ANTIMONY PENTAFLUORIDE INTERCALATED IN GRAPHITE AS CATALYSTS FOR REACTIONS OF THE FRIEDEL-CRAFTS TYPE

Antimony pentafluoride intercalated in graphite, produced by the reaction of gaseous antimony pentafluoride with powdered graphite in a flow-type system at 140-160 deg C, exhibits the characteristics of liquid antimony pentafluoride in the temperature range of 50-100 deg C and can be used as a catalyst for various processes of the Friedel-Crafts type.The alkylation (by 1-bromooctane, cyclohexene, cyclopentene, and acylation by capryloyl, benzoyl, and perfluorobutyryl chlorides) of benzene were realized.The oxidative characteristics of antimony pentafluoride were used for the generation of the polyatomic doubly charged sulfur cation and electrophilic reagents from polyfluorodiaryl disulfide, lead thiocyanate, and mercuric oxide and their introduction into reaction with benzene.

Organothallium compounds. VI. Reactions of bromobis(pentafluorophenyl)thallium(III) with main group elements

Bromobis(pentafluorophenyl)thallium(IlI) reacts with many main group elements on heating in the absence of a solvent to give pentafluorophenyl derivatsves of these elements. The compounds C6F5M (M = Cl, Br, or I), (C6F5)2M (M = Zn, Cd, Hg, S, Se or Te), (C6F5)3M (M = In, P, As, or Sb), and (C6F5)M (M = Ge or Sn) have been prepared by this method. Substantial decomposition of (C6F5)2TlBr occurs on reaction with aluminium, gallium, lead and bismuth, but pcntafluorophenyl derivatives of these elements are not obtained.