18064-78-3Relevant articles and documents
Diselenide-Mediated Catalytic Functionalization of Hydrophosphoryl Compounds
Handoko,Benslimane, Zacharia,Arora, Paramjit S.
, p. 5811 - 5816 (2020/07/27)
We report a diaryldiselenide catalyst for cross-dehydrogenative nucleophilic functionalization of hydrophosphoryl compounds. The proposed organocatalytic cycle closely resembles the mechanism of the Atherton-Todd reaction, with the catalyst serving as a recyclable analogue of the halogenating agent employed in the named reaction. Phosphorus and selenium NMR studies reveal the existence of a P-Se bond intermediate, and structural analyses indicate a stereospecific reaction.
Synthesis, chemistry, and characterization of perfluoroaromatic selenium derivatives
Klapoetke, Thomas M.,Krumm, Burkhard,Polborn, Kurt
, p. 1359 - 1366 (2007/10/03)
The reaction of perfluoroaryllithium RC6F4Li, where R = F or 4- CF3C6F4O, respectively, with selenium gives the known diselanes (RC6F4Se)2 (1a, 1b). Redox reactions of
Reactions of Monocyclopentadienyl Complexes of Molybdenum and Tungsten with Derivatives of Phenols and Pentafluorobenzeneselenol
Davidson, Jack L.,Holz, Birgit,Leverd, Pascal C.,Lindsell, W. Edward,Simpson, Nigel J.
, p. 3527 - 3532 (2007/10/02)
Reactions of (cp = η5-C5H5) with thallium salts Tl(OR) (R = aryl) in tetrahydrofuran did not produce simple substitution products but afforded reduced species 2, oxidised species or the thalliu
