97399-11-6Relevant articles and documents
Mn(salen)-catalyzed enantioselective C-H amination
Kohmura, Yoshinori,Katsuki, Tsutomu
, p. 3339 - 3342 (2001)
A chiral 3,3′,5,5′-tetrabromosubstituted (salen)manganese(III) complex was found to be an efficient catalyst for asymmetric C-H amination (up to 89% ee). In the reaction of cycloalkenes, allylic amination occurred in preference to aziridination.
SYNTHESIS OF PROTECTED ALLYLAMINES VIA PALLADIUM-CATALYZED AMIDE ADDITION TO ALLYLIC SUBSTRATES
Bystroem, Styrbjoern E.,Aslanian, Robert,Baeckvall, Jan-E.
, p. 1749 - 1752 (2007/10/02)
Palladium-catalyzed reaction of allylic substrates with sodium p-toluenesulfonamide leads to the N-allylic-p-toluenesulfonamides.The reaction takes place with retention of configuration at the allylic carbon.