97478-47-2

Upstream product

• 127-65-1 chloroamine-T 
• 4192-77-2 ethyl cinnamate 
• 623-73-4 diazoacetic acid ethyl ester 
• 51608-60-7 N-(benzylidene)-p-methylbenzenesulfonamide 
• 100-52-7 benzaldehyde 

Downstream Products

• 97478-49-4 3-Phenyl-1-(toluene-4-sulfonyl)-aziridine-2-carbaldehyde 
• 97478-38-1 5-ethenyl-2-phenyl-1-tosyl-3-pyrroline 
• 97478-23-4 2-((E)-Buta-1,3-dienyl)-3-phenyl-1-(toluene-4-sulfonyl)-aziridine 

Relevant academic research and scientific papers

1,3-dipolar cycloadditions of carbonyl ylides to aldimines: Scope, limitations and asymmetric cycloadditions

The development of a diastereoselective 1,3-dipolar cycloaddition of carbonyl ylides and imines for the synthesis of α-hydroxy-β-amino esters is described. The methodology is successfully applied to chiral α-methylbenzylimines affording enantiomerically p

Pd(0) PROMOTED TRANSFORMATION OF N-TOSYL-2-(1,3-BUTADIENYL)-AZIRIDINE INTO N-TOSYL-2-VINYL-3-PYRROLINE

1,3-Butadienylaziridines activated by N-tosyl group smoothly rearrange to vinylpyrrolidine derivates in the presence of a catalytic amount of Pd(PPh3)4.Transformation of dienylazetidines into vinylpiperidine derivatives is also described.