97579-93-6Relevant articles and documents
ATOM TRANSFER CYCLIZATION OF α-HALONITRILE AND α-HALOCARBONYL COMPOUNDS
Mori, Miwako,Kubo, Yukiko,Ban, Yoshio
, p. 433 - 436 (2007/10/02)
α-Halonitriles and α-haloesters reacted with internal olefin in the presence of KI to give cyclized products in good yields via radical intermediate. α-Iodonitrile 1b afforded 2b and 2b' merely upon heating.
PALLADIUM CATALYZED ENE-HALOGENOCYCLIZATION OF α-HALOESTER HAVING INTERNAL DOUBLE BOND WITH THE LOW-VALENT METAL COMPLEX
Mori, Miwako,Kubo, Yukiko,Ban, Yoshio
, p. 4321 - 4330 (2007/10/02)
α-Haloester having internal double bond was reacted with a catalytic amount of Pd(Ph3)4 to afford the cyclized product in good yield and the same product was obtained by treatment of ketene silyl acetal with divalent palladium complex.