97579-96-9

Upstream product

• 97579-92-5 2-Bromo-4-(cyclohex-2-enyl-phenoxycarbonyl-amino)-butyric acid ethyl ester 
• 1885-14-9 phenyl chloroformate 
• 1521-51-3 rac-3-bromocyclohexene 
• 97579-88-9 3-(N-2-cyclohexen-1-yl-N-phenoxycarbonylamino)-1-ethoxycarbonylpropane 
• 6937-16-2 ethyl γ-aminobutyrate hydrochloride 

Downstream Products

• 97580-02-4 (4R,4aS,8aS)-3,4,4a,7,8,8a-Hexahydro-2H-quinoline-1,4-dicarboxylic acid 4-ethyl ester 1-phenyl ester 
• 97580-02-4 3,4,4a,7,8,8a-Hexahydro-2H-quinoline-1,4-dicarboxylic acid 4-ethyl ester 1-phenyl ester 

Relevant academic research and scientific papers

PALLADIUM CATALYZED ENE-HALOGENOCYCLIZATION OF α-HALOESTER HAVING INTERNAL DOUBLE BOND WITH THE LOW-VALENT METAL COMPLEX

α-Haloester having internal double bond was reacted with a catalytic amount of Pd(Ph3)4 to afford the cyclized product in good yield and the same product was obtained by treatment of ketene silyl acetal with divalent palladium complex.

REACTION OF α-HALOESTER HAVING INTERNAL DOUBLE BOND WITH THE LOW-VALENT METAL COMPLEX

The α-haloester having an internal double bond was allowed to react with a catalytic amount of Pd(PPh3)4 to afford a cyclized product in a fairly good yield and the same product was obtained by treatment with Pd(OAc)2 to ketene silyl acetal.