97585-02-9

Basic information

• Product Name: (E)-dodec-2-enenitrile
• CAS NO: 97585-02-9
• Molecular Weight: 179.305
• Mol File: 97585-02-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (E)-dodec-2-enenitrile(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-dodec-2-enenitrile(97585-02-9)
• EPA Substance Registry System: (E)-dodec-2-enenitrile(97585-02-9)

Safety Data

• Hazardous Substances Data: 97585-02-9(Hazardous Substances Data)

Upstream product

• 2984-55-6 2-hydroxydodecanoic acid 
• 112-31-2 caprinaldehyde 
• 2537-48-6 diethyl 1-cyanomethylphosphonate 
• 22104-81-0 (2E)-dodec-2-en-1-ol 
• 20407-84-5 2-dodecenal 
• 2437-25-4 undecyl cyanide 
• 859201-80-2 2-bromo-dodecanenitrile 

Relevant articles and documents

A Transition-Metal-Free One-Pot Cascade Process for Transformation of Primary Alcohols (RCH2OH) to Nitriles (RCN) Mediated by SO2F2

A new transition-metal-free one-pot cascade process for the direct conversion of alcohols to nitriles was developed without introducing an “additional carbon atom”. This protocol allows transformations of readily available, inexpensive, and abundant alcohols to highly valuable nitriles.

Palladium-Catalyzed α,β-Dehydrogenation of Esters and Nitriles

A highly practical and general palladium-catalyzed methodology for the α,β-dehydrogenation of esters and nitriles is reported. Generation of a zinc enolate or (cyanoalkyl)zinc species followed by the addition of an allyl oxidant and a palladium catalyst results in synthetically useful yields of α,β-unsaturated esters, lactones, and nitriles. Preliminary mechanistic investigations are consistent with reversible β-hydride elimination and turnover-limiting, propene-forming reductive elimination.