97779-20-9Relevant academic research and scientific papers
3-BROMO-2-t-BUTYLSULFONYL-1-PROPENE. A VERSATILE MULTI-COUPLING REAGENT PART 1
Auvray, P.,Knochel, P.,Normant, J.F.
, p. 4495 - 4508 (2007/10/02)
The 3-bromo-2-t-butylsulfonyl-1-propene 3 was prepared in two steps from allyl-t-butylthioether in 70 percent overall yield.This reagent reacts selectively with a broad range of nucleophiles (amine, thiolate, lithium ester- and keto- enolates, magnesium,
3-Bromo-2-(tert-butylsulfonyl)-1-propene. A multi-coupling reagent. Part 2.
Auvrat, P.,Knochel, P.,Normant, J. F.
, p. 2329 - 2332 (2007/10/02)
3-bromo-2-(tert-butylsulfonyl)-1-propene 1 reacts in good yields with various electrophile (aldehydes, ketones, nitriles and alkynes) in the presence of zinc metal to give unsaturated sulfones of type 4.These compounds can further react with soft or hard
