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2-chloro-N-(4-nitrobenzyl)benzenamine is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

97801-03-1

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97801-03-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 97801-03-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,7,8,0 and 1 respectively; the second part has 2 digits, 0 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 97801-03:
(7*9)+(6*7)+(5*8)+(4*0)+(3*1)+(2*0)+(1*3)=151
151 % 10 = 1
So 97801-03-1 is a valid CAS Registry Number.

97801-03-1Relevant articles and documents

Photosensitized Diels-Alder reactions of N-arylimines: Synthesis of tetrahydroquinoline derivatives

Zhang, Wei,Jia, Xiaodong,Yang, Li,Liu, Zhong-Li

, p. 9433 - 9436 (2002)

Irradiation (λ>345 nm) of catalytic amounts of 2,4,6-triphenylpyrylium tetrafluoroborate (TPT) in a CH2Cl2 solution of N-aryl imines and α-methylstyrene or styrene produced the corresponding [4+2] cycloaddition products, tetrahydroquinoline derivatives, in good yield. The reaction was controlled by the relative oxidation potentials of the dienophile and the diene.

A simple method for the reduction of Schiff bases using biosynthesized nickel oxide nanoparticles

Muthuvinothini, Alagesan,Stella, Selvaraj

, p. 267 - 271 (2020/07/07)

An innovative and simple approach for the reduction of aldimines to the corresponding secondary amines was described using biosynthesized nickel oxide nanoparticles as heterogeneous catalyst and ammonium formate as the hydrogen donor. This catalytic trans

Synthesis of some novel 2-substituted benzothiazole derivatives containing benzylamine moiety as monoamine oxidase inhibitory agents

Kaya, Betül,Sa?l?k, Begüm Nurpelin,Levent, Serkan,?zkay, Yusuf,Kaplanc?kl?, Zafer As?m

, p. 1654 - 1661 (2016/10/09)

In the present work, 12 new 2-(5-substituted-benzothiazol-2-ylsulfanyl)-N-(substitutedbenzyl)-N-(4-substitutedphenyl) acetamide derivatives (4a–l) was designed and synthesized. The structures of the synthesized compounds were clarified using Fourier trans

Efficient and chemoselective direct reductive amination of aromatic aldehydes catalyzed by oxo-rhenium complexes containing heterocyclic ligands

Bernardo, Joana R.,Sousa, Sara C.A.,Florindo, Pedro R.,Wolff, Mariusz,Machura, Barbara,Fernandes, Ana C.

, p. 9145 - 9154 (2013/09/24)

This work describes the catalytic activity of 17 oxo-rhenium complexes containing heterocyclic ligands in the direct reductive amination of 4-nitrobenzaldehyde with 4-chloroaniline, using phenylsilane as reducing agent. In general, all of the catalysts tested gave excellent yields of the secondary amine, although, the best result was obtained with the catalytic system PhSiH3/ReOBr2(Hhmpbta)(PPh3) (2.5 mol %). This system was also applied to the synthesis of a large variety of secondary amines in good to excellent yields and tertiary amines in moderate yields, with tolerance of different functional groups.

Molecular iodine catalyzed transfer hydrogenation: Reduction of aldimines, ketimines, and α-imino esters

Bachu, Prabhakar,Zhu, Chen,Akiyama, Takahiko

supporting information, p. 3977 - 3981 (2013/07/25)

An efficient and practical protocol for the reduction of aldimines, ketimines, and α-imino esters in the presence of catalytic amount of molecular iodine with Hantzsch ester at ambient temperature afforded the corresponding amines in excellent yields.

Highly selective mono-N-benzylation and amidation of amines with alcohols or carboxylic acids using the Ph2PCl/I2/imidazole reagent system

Nowrouzi, Najmeh,Jonaghani, Mohammad Zareh

experimental part, p. 498 - 509 (2012/07/30)

Chlorodiphenylphosphine, imidazole, and molecular iodine in refluxing dichloromethane are used for the efficient preparation of amides under mild reaction conditions. This reagent system also shows excellent selectivity for mono-N-alkylation of amines with alcohols. In this system, the resulting phosphorus byproduct (diphenylphosphinic acid) is easily removed by extraction using an aqueous basic solution in the workup processes, which avoids the tedious and time-consuming chromatographic methods.

N-heterocyclic carbene boranes are good hydride donors

Horn, Markus,Mayr, Herbert,Lacote, Emmanuel,Merling, Everett,Deaner, Jordan,Wells, Sarah,McFadden, Timothy,Curran, Dennis P.

experimental part, p. 82 - 85 (2012/02/16)

The nucleophilicity parameters (N) of 1,3-bis(2,6-diisopropylphenyl) imidazol-2-ylidene borane and 1,3-dimethylimidazol-2-ylidene borane are 9.55 and 11.88. This places N-heterocyclic carbene boranes (NHC-boranes) among the most nucleophilic classes of neutral hydride donors. Reductions of highly electron-poor C=N and C=C bonds provide hydrogenation products along with new, stable borylated products. The results suggest that NHC-boranes have considerable untapped potential as neutral organic reductants.

Br?nsted acid catalyzed reductive amination with benzothiazoline as a highly efficient hydrogen donor

Zhu, Chen,Akiyama, Takahiko

supporting information; experimental part, p. 1251 - 1254 (2011/06/28)

Reductive amination of aldehyde and amine proceeded smoothly in the presence of benzothiazoline as efficient hydrogen source by means of 20 mol% trifluoroacetic acid to give the corresponding amines in excellent yields. Hydrogen-donor abilities of benzothiazoline, benzimidazoline, and benzoxazoline were compared. Georg Thieme Verlag Stuttgart - New York.

New heteroaromatic azo compounds based on pyridine, isoxazole, and benzothiazole for efficient and highly selective amidation and mono-N-benzylation of amines under Mitsunobu conditions

Iranpoor, Nasser,Firouzabadi, Habib,Khalili, Dariush

experimental part, p. 923 - 934 (2010/10/01)

4,4′-Azopyridine (2c) is used in conjunction with triphenylphosphine for the efficient conversion of carboxylic acids into amides via Mitsunobu reaction with primary and secondary aliphatic and aromatic amines. The highly selective amidation of only primary aromatic amines with new heterogeneous azo compounds based on benzothiazole 2d and isoxazole 2e is also described. These azo compounds 2c-2e can also be applied for selective mono-N-benzylation of primary aromatic amines. The solid side product heteroaromatic hydrazines obtained under the developed Mitsunobu conditions are easily separated by simple filtration and can be reoxidized to azo compounds for further use.

Gallium(III) triflate catalyzed direct reductive amination of aldehydes

Surya Prakash,Do, Clement,Mathew, Thomas,Olah, George A.

experimental part, p. 111 - 117 (2010/11/05)

Direct hydroamination of aldehydes and ketones provides one-step entry into desired α-aminoalkane derivatives which are important synthons for many biologically active molecules. The reductive amination of aldehydes in the presence of silanes has been eff

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