98066-00-3Relevant academic research and scientific papers
Chemoenzymatic synthesis of (E)-3,7-dimethyl-2-octene-1,8-diol isolated from the hairpencils of male Danaus chrysippus (African Monarch)
Takabe, Kunihiko,Mase, Nobuyuki,Hashimoto, Hiroya,Tsuchiya, Atsushi,Ohbayashi, Takashi,Yoda, Hidemi
, p. 1967 - 1969 (2007/10/03)
The synthesis of (E)-3,7-dimethyl-2-octene-1,8-diol (1), which was isolated from the hairpencils of male Danaus chrysippus (African Monarch), was investigated. The key step of the sequence involves asymmetric desymmetrization of the 1,3-propanediol 7 with
Highly Stereoselective Total Synthesis of Plaunotol
Sato, Kikumasa,Miyamoto, Osamu,Inoue, Seiichi,Iwase, Norimichi,Honda, Kiyoshi
, p. 1433 - 1436 (2007/10/02)
Highly stereoselective total synthesis of plaunotol has been achieved by the application of the (Z)-stereoselective direct Wittig olefination to α-alkoxy ketones having geranylacetone skeleton.
The Synthesis of Cembranolide Precursors via Addition of Allylstannanes to Conjugated Aldehydes
Marshall, James A.,DeHoff, Bradley S.
, p. 863 - 872 (2007/10/02)
The Lewis acid promoted addition of functionalized allylstannanes A9, C10, and C11 to a variety of conjugated aldehydes was examined as a possible route to acyclic precursors of macrocyclic diterpenoids.Additions to crotonaldehyde proceeded as expected, g
Total Syntheses of Fungal Metabolites and Functionalized Furanones
Chen, Kau-Ming,Semple, J. Edward,Joullie, Madeleine M.
, p. 3997 - 4005 (2007/10/02)
Simple, efficient syntheses of the fungal metabolites colletochlorin D and (+/-)-ascofuranone and one of its stereoisomers are described.Our investigations of functionalized furanones also enabled us to develop a nine-step (22percent overall yield) synthe
