98078-18-3

Upstream product

• 98078-17-2 7-hydroxyheptanophenone tosylhydrazone 
• 100-52-7 benzaldehyde 
• 68760-65-6 (6-hydroxyhexyl)triphenylphosphonium bromide 
• 629-11-8 1,6-hexanediol 
• 103202-59-1 6-(tert-butyldimethylsilyl)oxyhexan-1-ol 
• 118794-69-7 6-[(tert-butyldimethylsilyl)oxy]hexanal 
• 69049-76-9 (6-((tetrahydro-2H-pyran-2-yl)oxy)hexyl)magnesium chloride 
• 263565-77-1 7-hydroxy-1-phenyl-heptan-1-one 
• 50889-29-7 (5-carboxypentyl)triphenylphosphonium bromide 
• 5771-68-6 7-phenyl-6-heptenoic acid 

Downstream Products

• 128870-44-0 (Z)-7-phenyl-(Z)-1-(triisopropylsiloxy)-1,6-heptadiene 
• 128870-43-9 (E)-7-phenyl-(Z)-1-(triisopropylsiloxy)-1,6-heptadiene 
• 56020-75-8 (E)-7-phenyl-6-heptenal 
• 56020-76-9 (Z)-7-phenyl-6-heptenal 
• 21592-61-0 (E,Z)-7-phenyl-6-heptenal 

Relevant academic research and scientific papers

Stereoselective Rhodium-Catalyzed Isomerization of Stereoisomeric Mixtures of Arylalkenes

A new efficient method for the synthesis of a high ratio of E -alkenes from E / Z mixtures of alkenes with B 2pin 2in the presence of a rhodium catalyst is described. This reaction features mild reaction conditions, broad functional group tolerance, and highly great application potential.

Synthesis and nematocidal activity of aralkyl- and aralkenylamides related to piperamide on second-stage larvae of Toxocara canis

Seventy-nine aralkyl- and aralkenylamides related to piperamides were synthesized and their nematocidal activity against second-stage larvae of dog roundworm, Toxocara canis, was examined. The activity was greatly dependent on the alkyl chain length and the nature of the amine moiety, but was scarcely affected by the presence or absence of double bond(s) in the chain. The alkyl chain lengths which showed the strongest activity in a series of homologues were m=11 for the pyrrolidine amides and m=13 for the N- methylpiperazine amides. Although piperamides (3,4-methylenedioxyphenyl homologues) showed the strongest activity among the homologues tested, methoxy substituent(s) on the aromatic ring did not have much effect on the activity. However, conversion of the methoxy group to a hydroxy group greatly decreased the activity and shortened the chain length giving the strongest activity. Calculated log P values of non-phenolic aryl-piperamides fell in the range from 3.5 to 4.5, whereas those of hydroxyphenyl-piperamides were smaller, suggesting that different mechanisms are involved in the nematocidal activity of phenolic and non-phenolic compounds.

A NOVEL CYCLIZATION REACTION OF OXIDO DIAZOALKANES: FORMATION OF 1-SUBSTITUTED CYCLOALKENES

The thermal decomposition of dialkali metal salts of δ-hydroxybutyl ketone and ε-hydroxypentyl ketone tosylhydrazones in diglyme at 80-120 deg C produced the 1-substituted cyclopentene and cyclohexene, respectively.