98184-34-0Relevant academic research and scientific papers
A new convenient synthesis of N-acyl-2-(dimethoxyphosphoryl)glycinates
Mazurkiewicz, Roman,Ku?nik, Anna
, p. 3439 - 3442 (2007/10/03)
Easily accessible N-acyl-2-triphenylphosphonioglycinate tetrafluoroborates react smoothly with trimethylphosphite in the presence of methyltriphenylphosphonium iodide to give N-acyl-2-(dimethoxyphosphoryl)glycinates in good or very good yields. The dimeth
4-Phosphoranylidene-5(4H)-oxazolones - A Novel Synthesis and Properties
Mazurkiewicz,Pierwocha
, p. 219 - 225 (2007/10/03)
4-Phosphoranylidene-5(4H)-oxazolones (2), a hardly known class of phosphorus ylides, were readily prepared from 4-unsubstituted-5-(4H)-oxazolones (1) by treatment with Ph3P-Br2, Bu3P-Br2, Ph3P-CCl4, or Ph3P-CBr4 adducts in the presence of triethylamine in CH2Cl2 at room temperature in a novel, efficient one-pot procedure. The spectroscopic properties of the ylides are reported and discussed.
Structure and Prperties of Phosphonium Ylides-Betaines, Derivatives of 2-phenyl-2-oxazolin-5-one and its Thio- and Seleno-analogues
Meervelt, Luc Van,Schuerman, Geertrui S.,Brovarets, Vladimir S.,Mishchenko, Nikolai I.,Romanenko, Evgenii A.,Drach, Boris S.
, p. 1471 - 1482 (2007/10/02)
The combined chemical, spectral, and X-ray structural investigation has shown that the structure and properties of mesomeric triphenylphosphonium ylides containing the 5-oxo-2-phenyl-4-oxazolidene moiety undergo considerable changes when the carbonyl oxyg
