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METHYL 4-(3-OXO-3-PHENYL-1-PROPENYL) BENZOATE is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

98258-72-1

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98258-72-1 Usage

Synthesis Reference(s)

Synthetic Communications, 15, p. 279, 1985 DOI: 10.1080/00397918508063800

Check Digit Verification of cas no

The CAS Registry Mumber 98258-72-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 9,8,2,5 and 8 respectively; the second part has 2 digits, 7 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 98258-72:
(7*9)+(6*8)+(5*2)+(4*5)+(3*8)+(2*7)+(1*2)=181
181 % 10 = 1
So 98258-72-1 is a valid CAS Registry Number.
InChI:InChI=1/C17H14O3/c1-20-17(19)15-10-7-13(8-11-15)9-12-16(18)14-5-3-2-4-6-14/h2-12H,1H3/b12-9+

98258-72-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name METHYL 4-(3-OXO-3-PHENYL-1-PROPENYL) BENZOATE

1.2 Other means of identification

Product number -
Other names Methyl 4-(3-Oxo-3-Phenyl-1-Propenyl) Benzoate (NMR)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:98258-72-1 SDS

98258-72-1Relevant academic research and scientific papers

Fluorescent Molecular Logic Gates Driven by Temperature and by Protons in Solution and on Solid

West, Matthew E. S.,Yao, Chao-Yi,Melaugh, Gavin,Kawamoto, Kyoko,Uchiyama, Seiichi,de Silva, A. Prasanna

supporting information, p. 13268 - 13274 (2021/08/06)

Temperature-driven fluorescent NOT logic is demonstrated by exploiting predissociation in a 1,3,5-trisubstituted Δ2-pyrazoline on its own and when grafted onto silica microparticles. Related Δ2-pyrazolines become proton-driven YES an

Borane-Catalyzed, Chemoselective Reduction and Hydrofunctionalization of Enones Enabled by B-O Transborylation

Nicholson, Kieran,Langer, Thomas,Thomas, Stephen P.

supporting information, p. 2498 - 2504 (2021/04/13)

The use of stoichiometric organoborane reductants in organic synthesis is well established. Here these reagents have been rendered catalytic through an isodesmic B-O/B-H transborylation applied in the borane-catalyzed, chemoselective alkene reduction and formal hydrofunctionalization of enones. The reaction was found to proceed by a 1,4-hydroboration of the enone and B-O/B-H transborylation with HBpin, enabling catalyst turnover. Single-turnover and isotopic labeling experiments supported the proposed mechanism of catalysis with 1,4-hydroboration and B-O/B-H transborylation as key steps.

Rh(II)-Catalyzed Nitrene-Transfer [5 + 1] Cycloadditions of Aryl-Substituted Vinylcyclopropanes

Combee, Logan A.,Johnson, Shea L.,Laudenschlager, Julie E.,Hilinski, Michael K.

supporting information, p. 2307 - 2311 (2019/04/10)

Formal [5 + 1] cycloadditions between aryl-substituted vinylcyclopropanes and nitrenoid precursors are reported. The method, which employs Rh2(esp)2 as a catalyst, leads to the highly regioselective formation of substituted tetrahydropyridines. Preliminary mechanistic studies support a stepwise, polar mechanism enabled by the previously observed Lewis acidity of Rh-nitrenoids. Overall, this work expands the application of nitrene-transfer cycloaddition, a relatively underexplored approach to heterocycle synthesis, to the formation of six-membered rings.

CBr4 as a Halogen Bond Donor Catalyst for the Selective Activation of Benzaldehydes to Synthesize α,β-Unsaturated Ketones

Kazi, Imran,Guha, Somraj,Sekar, Govindasamy

supporting information, p. 1244 - 1247 (2017/03/14)

CBr4 has been employed as a halogen bond donor catalyst for the selective activation of aldehyde, to achieve an efficient solvent- and metal-free CC bond forming reaction in the presence of strong acid sensitive groups such as methoxy, cyanide, ester, and ketal for the synthesis of α,β-unsaturated ketones. This unique capability of CBr4 to act as a halogen bond donor has been explored and established using UV-vis as well as IR spectroscopy. Moreover, this unprecedented methodology enables the synthesis of the pharmaceutically important molecule licochalcone A.

Synthesis of chalcones via domino dehydrochlorination/Pd(OAc)2-catalyzed Heck reaction

Guo, Tenglong,Jiang, Quanbin,Yu, Likun,Yu, Zhengkun

, p. 78 - 85 (2015/09/28)

A new method has been developed for the cross-coupling of aryl halides with β-chloroalkyl aryl ketones and their ester and amide analogs through a domino dehydrochlorination/Pd(OAc)2- catalyzed Heck reaction sequence. The enone intermediates generated in situ reduced the occurrence of side reactions and therefore enhanced the efficiency of the reaction. This reaction exhibited good tolerance to various functional groups on both substrates and provides rapid access to a wide range of chalcone derivatives.

Inhibitors of histone deacetylase

-

, (2008/06/13)

The invention relates to the inhibition of histone deacetylase. The invention provides compounds and methods for inhibiting histone deacetylase enzymatic activity. The invention also provides compositions and methods for treating cell proliferative diseases and conditions.

ALDOL CONDENSATIONS ON BASIC ALUMINA: THE FACILE SYNTHESES OF CHALCONES AND ENONES IN A SOLVENT-FREE MEDIUM

Varma, Rajender S.,Kabalka, George W.,Evans, Lan T.,Pagni, Richard M.

, p. 279 - 284 (2007/10/02)

The condensation of benzaldehyde derivatives with ketones was carried out on basic alumina in the absence of solvents.The reaction provides a facile entry into the chalcone and enone systems.

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