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Benzophenone azine, also known as diphenylketene imine, is an organic compound that belongs to the family of azine compounds. It is characterized by its yellow to orange solid appearance and its solubility in organic solvents, while being insoluble in water. BENZOPHENONE AZINE is recognized for its versatile applications in various industrial processes, particularly in the realm of polymer synthesis, photolithography, and the production of dyes, pigments, and pharmaceuticals. Furthermore, benzophenone azine has garnered interest for its potential as a reagent in organic chemistry and as a photostabilizer in plastics and coatings.

983-79-9

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983-79-9 Usage

Uses

Used in Polymer Synthesis:
Benzophenone azine is used as a photochemical initiator for the synthesis of polymers. It facilitates the polymerization process by initiating the reaction upon exposure to light, which is crucial for the production of various polymeric materials with specific properties.
Used in Photolitography Processes:
In the semiconductor industry, benzophenone azine serves as a key component in photolithography, where it helps in the transfer of patterns onto a substrate. Its photochemical properties allow for precise patterning, which is essential for the manufacturing of microelectronic devices.
Used in Dye and Pigment Production:
Benzophenone azine is utilized in the production of dyes and pigments due to its color-yielding properties. It contributes to the creation of a wide range of colors in various applications, including textiles, plastics, and printing inks.
Used in Pharmaceutical Industry:
Benzophenone azine is used as an intermediate in the synthesis of certain pharmaceutical compounds. Its unique chemical structure allows it to be a building block for the development of new drugs with potential therapeutic applications.
Used in Organic Chemistry as a Reagent:
Benzophenone azine has been studied for its potential use as a reagent in organic chemistry. Its ability to participate in various chemical reactions makes it a valuable tool for the synthesis of complex organic molecules.
Used as a Photostabilizer in Plastics and Coatings:
Benzophenone azine is employed as a photostabilizer to protect plastics and coatings from the degrading effects of sunlight. Its ability to absorb and dissipate UV radiation helps in extending the lifespan and maintaining the appearance of these materials.

Check Digit Verification of cas no

The CAS Registry Mumber 983-79-9 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 9,8 and 3 respectively; the second part has 2 digits, 7 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 983-79:
(5*9)+(4*8)+(3*3)+(2*7)+(1*9)=109
109 % 10 = 9
So 983-79-9 is a valid CAS Registry Number.
InChI:InChI=1/C26H20N2/c1-5-13-21(14-6-1)25(22-15-7-2-8-16-22)27-28-26(23-17-9-3-10-18-23)24-19-11-4-12-20-24/h1-20H

983-79-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name N-(benzhydrylideneamino)-1,1-diphenylmethanimine

1.2 Other means of identification

Product number -
Other names Diphenylketazine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:983-79-9 SDS

983-79-9Relevant academic research and scientific papers

Synthesis of 3-(2-Oxo-2,3-dihydrobenzo[b]furan-3-ylidenehydrazono)-2,3- dihydrobenzo[b]furan-2-one

Pulina,Zalesov,Kataev

, p. 861 - 863 (2007)

Reactions of benzophenone and fluoren-9-one hydrazones with (2-hydroxyphenyl)oxoacetic acid gave [carboxy(2-hydroxyphenyl) methylidenehydrazono](2-hydroxyphenyl)acetic acid which underwent intramolecular cyclization with formation of 3-(2-oxo-2,3-dihydrob

Synthesis of symmetrical and asymmetrical azines from hydrazones and/or ferrocenecarboxaldehyde as potential antimicrobial–antitumor agents

Lasri, Jamal,Aly, Magda M.,Eltayeb, Naser Eltaher,Babgi, Bandar A.

, p. 1 - 8 (2018)

9-Fluorenone azine 2a and benzophenone azine 2b were synthesized, respectively, by treatment of 9-fluorenone hydrazone 1a or benzophenone hydrazone 1b with FeCl3 in chloroform. Ferrocenecarboxaldehyde 3 reacts with 1a or 1b, in ethanol, to furn

Cobalt(II) complex of a diazoalkane radical anion

Bonyhady, Simon J.,Goldberg, Jonathan M.,Wedgwood, Nicole,Dugan, Thomas R.,Eklund, Andrew G.,Brennessel, William W.,Holland, Patrick L.

, p. 5148 - 5150 (2015)

β-Diketiminate cobalt(I) precursors react with diphenyldiazomethane to give a compound that is shown by computational studies to be a diazoalkane radical anion antiferromagnetically coupled to a high-spin cobalt(II) ion. Thermolysis of this complex result

Iron and Cobalt Diazoalkane Complexes Supported by β-Diketiminate Ligands: A Synthetic, Spectroscopic, and Computational Investigation

Bonyhady, Simon J.,Derosha, Daniel E.,Vela, Javier,Vinyard, David J.,Cowley, Ryan E.,Mercado, Brandon Q.,Brennessel, William W.,Holland, Patrick L.

, p. 5959 - 5972 (2018)

Diazoalkanes are interesting redox-active ligands and also precursors to carbene fragments. We describe a systematic study of the binding and electronic structure of diphenyldiazomethane complexes of β-diketiminate supported iron and cobalt, which span a

Preparation and application of 5-bromoquinazoline derivative

-

Paragraph 0035-0037, (2021/02/16)

The invention discloses a 5-bromoquinazoline derivative shown in the corresponding formula. A synthesis method of the 5-bromoquinazoline derivative compound (I) comprises the following steps: weighing1.18 g of 5-bromoisatin, 2.5503g of ammonium formate an

Preparation and application of chiral quaternary ammonium salt

-

Paragraph 0039-0041, (2021/08/07)

The invention provides preparation of chiral quaternary ammonium salt. The structural formula is as follows: a synthesis method of the chiral quaternary ammonium salt compound (I) comprises the following steps: using 10 mol% zinc chloride as a catalyst, firstly adding 22 mmol of anhydrous ZnCl2, 50 mL of absolute methanol, 2.1639 g of sodium hydroxide and 1.5656 g of D-valinol, refluxing the mixture at high temperature for 60 h, stopping the reaction, dissolving the residue with water, extracting with CH2Cl2 (20 mL * 3), drying the organic phase with anhydrous sodium sulfate, rotating to remove the solvent, and recrystallizing the crude product with dichloromethane and absolute ethyl alcohol to obtain a colorless crystal; the application of the chiral quaternary ammonium salt compound (I) is characterized in that the chiral quaternary ammonium salt compound has good catalytic performance in a nitrile silicification reaction of benzaldehyde and a condensation reaction of benzophenone hydrazone, and the conversion rates respectively reach up to 71% and 99%.

Formation of Osmium Alkylidene, Alkylidyne, and Dinitrogen Complexes from Reactions of OsCl2(PPh3)3with Diazoalkanes

Cui, Mingxu,Jia, Guochen,Sung, Herman H. Y.,Williams, Ian D.

, p. 3833 - 3842 (2021/11/18)

The reactions of OsCl2(PPh3)3 with a series of diazoalkanes were investigated. The reactions with monosubstituted diazoalkanes N2CHR gave the desired osmium alkylidene complexes OsCl2(=CHR)(PPh3)2, the stability of which is dependent on the substituent on the alkylidene carbons. The five-coordinate osmium alkylidene complex OsCl2(=CHCOOMe)(PPh3)2 is thermally stable, whereas the analogous complex OsCl2(=CH-p-tol)(PPh3)2 readily rearranges to its hydrido-alkylidyne form OsHCl2(C-p-tol)(PPh3)2. A substitution reaction of OsCl2(=CHCOOMe)(PPh3)2 with PCy3 produced the hydrido-alkylidyne complex OsHCl2(CCOOMe)(PCy3)2, revealing the effect of the phosphine on the relative stability of OsCl2(=CHCOOMe)(PR3)2 and OsHCl2(CCOOMe)(PR3)2. The reaction of OsCl2(PPh3)3 with the acceptor-acceptor disubstituted diazoalkane dibenzoyl diazomethane, bearing COPh substituents, led to the formation of the metallacyclic complex OsCl2{κ2-N,O-[N2C(COPh)C(Ph)O]}(PPh3)2 due to the chelating effect of dibenzoyl diazomethane. The complex OsCl2(PPh3)3 catalyzed the homocoupling of the diazoalkane N2CPh2 to give the azine Ph2C=N-N=CPh2. The η1-N2 coordinated binuclear complex (Ph3P)2ClOs(μ-Cl)3Os(PPh3)2(N2) was isolated as a minor product, which was considered to be an off-cycle product in the catalytic reaction.

Grignard reagent dictated copper(I) phosphines catalyzed reductive coupling of diazo compounds: The chemistry beyond carbene generation

Kuzhalmozhi Madarasi, Packirisamy,Sivasankar, Chinnappan

, (2021/12/01)

Copper-dppf catalyzed reductive coupling of diazo compounds through terminal nitrogen is reported. However, copper catalysts are known to produce carbene from diazo compounds; the reaction conditions played an important role in the formation of diazine over carbene generation. Several control experiments have been conducted to understand the reaction mechanism and found that the formation of a copper–Mg heterobimetallic complex would be responsible for the observed reactivity pattern. The reaction produced diazine as a reductive coupling product along with biphenyl as a by-product. All the synthesized diazines have been characterized fully by using analytical and spectroscopic techniques.

Palladium-Catalyzed Regioselective Acylation of Diazines with Toluenes: A New Approach to the Synthesis of ortho-Diacylbenzenes

Afaridoun, Hadi,Kianmehr, Ebrahim,Seifinoferest, Behnoush

supporting information, (2020/08/13)

A highly efficient and practical procedure for chemo- and regioselective synthesis of ortho-diacylbenzenes through Pd-catalyzed oxidative C–H bond activation has been developed. Using this method, a variety of ortho-diacylbenzenes were prepared in moderate to good yields, by direct acylation of diazines with toluene derivatives as acylation source. Ortho-diacylbenzenes may be used as precursors in synthesis of pharmaceuticals and agrochemicals.

Application of chiral oxazoline-copper complex

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Page/Page column 8, (2020/01/25)

An application of a bis{2-[4(R)-phenyl-4,5-dihydro]-2-oxazoline}phenol-copper complex with a chemical formula shown in the description is characterized in that the complex has a good catalysis performance when used as a catalyst for a reaction of diphenyl

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