Benzophenone azine

Base Information

• Chemical Name: Benzophenone azine
• CAS No.: 983-79-9
• Molecular Formula: C26H20N2
• Molecular Weight: 360.458
• Hs Code.: 2928000090
• European Community (EC) Number: 621-558-7
• NSC Number: 401226
• DSSTox Substance ID: DTXSID50243546
• Nikkaji Number: J123.957K
• Mol file: 983-79-9.mol

Synonyms:Benzophenone azine;983-79-9;Benzophenone, azine;Diphenylketazine;BENZOPHENONEAZINE;N-(benzhydrylideneamino)-1,1-diphenylmethanimine;Methanone, diphenyl-, (diphenylmethylene)hydrazone;1,2-bis(diphenylmethylene)hydrazine;Diphenylmethanone (diphenylmethylene)hydrazone;Benzophenone, azine (6CI,7CI,8CI);Azinobis(diphenylmethane);Bis(diphenylmetylidene)hydrazine;SCHEMBL3272106;DTXSID50243546;MFCD00022006;NSC401226;AKOS015900581;Methanone, (diphenylmethylene)hydrazone;NSC 401226;NSC-401226;LS-91249;FT-0622724;Diphenylmethanone (diphenylmethylene)hydrazone #

Chemical Property of Benzophenone azine

Chemical Property:

• Vapor Pressure: 3.9E-09mmHg at 25°C
• Refractive Index: 1.598
• Boiling Point: 486.3 °C at 760 mmHg
• Flash Point: 240.8 °C
• PSA: 24.72000
• Density: 1.04 g/cm³
• LogP: 5.97660
• XLogP3: 7.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 360.162648646
• Heavy Atom Count: 28
• Complexity: 423

Purity/Quality:

98%,99%, ^*data from raw suppliers

BENZOPHENONE AZINE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(=NN=C(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of Benzophenone azine

There total 213 articles about Benzophenone azine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

C21H14N2O2 → benzophenone (119-61-9) + hexachloroethane (67-72-1) + p-chlorophenyl isocyanide (1885-81-0) + benzophenone azine (983-79-9)

Guidance literature:

With tetrachloromethane; Yields of byproduct given; Ambient temperature; Irradiation;

DOI:10.1016/S0040-4039(00)82327-8

Reference yield: 92.0%

C24H22N2O3 (115975-16-1) → benzophenone (119-61-9) + hexachloroethane (67-72-1) + N-(β-Chlor-isopropyl)benzamid (84967-87-3) + benzophenone azine (983-79-9)

Guidance literature:

With tetrachloromethane; Yields of byproduct given; Ambient temperature; Irradiation;

DOI:10.1016/S0040-4039(00)82327-8

Reference yield: 88.0%

diazodiphenylmethane (908093-98-1) → benzophenone (119-61-9) + Diphenylmethane (101-81-5) + benzophenone hydrazone (5350-57-2) + benzophenone azine (983-79-9) + N-benzhydrylbenzophenone hydrazone (25022-93-9)

Guidance literature:

With 2,2,2-trifluoroethanol; tetrabutylammonium perchlorate; In N,N-dimethyl-formamide; Product distribution; Ambient temperature; electrolytic reduction; other reagents, reagent ratio, potentials;

DOI:10.1021/ja00547a007

upstream raw materials:

4-aminourazole

benzophenone

1,2-bis[chloro(phenyl)methylidene]hydrazone

benzophenone hydrazone

Downstream raw materials:

2,2,3,3-tetraphenyl-aziridine

2-(2,2-Diphenyl-1-ethen-1-yl)-4,4-dimethyl-Δ1-pyrrolin

benzophenone

diphenylmethanol trifluoroacetate

Refernces

• 1、 Lasri, Jamal,Aly, Magda M.,Eltayeb, Naser Eltaher,Babgi, Bandar A.. "Synthesis of symmetrical and asymmetrical azines from hydrazones and/or ferrocenecarboxaldehyde as potential antimicrobial–antitumor agents". . p. 1 - 8. Retrieved 2018.
• 2、 Bonyhady, Simon J.,Derosha, Daniel E.,Vela, Javier,Vinyard, David J.,Cowley, Ryan E.,Mercado, Brandon Q.,Brennessel, William W.,Holland, Patrick L.. "Iron and Cobalt Diazoalkane Complexes Supported by β-Diketiminate Ligands: A Synthetic, Spectroscopic, and Computational Investigation". . p. 5959 - 5972. Retrieved 2018.
• 3、 -. "Preparation and application of chiral quaternary ammonium salt". Paragraph 0039-0041. . Retrieved 2021/08/07.
• 4、 Kuzhalmozhi Madarasi, Packirisamy,Sivasankar, Chinnappan. "Grignard reagent dictated copper(I) phosphines catalyzed reductive coupling of diazo compounds: The chemistry beyond carbene generation". . . Retrieved 2021/12/01.