98369-84-7Relevant academic research and scientific papers
New preparation of benzylic zinc reagents via a fragmentation reaction
Piazza, Claudia,Millot, Nicolas,Knochel, Paul
, p. 88 - 95 (2007/10/03)
The fragmentation of sterically hindered homobenzylic zinc alcoholates proceeds readily leading to benzylic zinc reagents free from any Wurtz-coupling product. Reaction of these organometallic intermediates with various aldehydes produces new homobenzylic
NOVEL SYNTHESIS OF BENZYLLITHIUMS FROM BENZYLSELENIDES
Clarembeau, M.,Krief, A.
, p. 1093 - 1096 (2007/10/02)
Benzylselenides are found to be valuable precursors of benzyllithiums.The scope of the new method is disclosed.
