98386-20-0Relevant academic research and scientific papers
MILD DEPROTECTION OF METHOXYMETHYL, METHYLTHIOMETHYL, METHOXYETHOXYMETHYL, AND β-(TRIMETHYLSILYL)ETHOXYMETHYL ESTERS WITH MAGNESIUM BROMIDE IN ETHER
Kim, Sunggak,Park, Young Hee,Kee, In Seo
, p. 3099 - 3100 (2007/10/02)
MOM, MTM, MEM, and SEM esters are cleanly deprotected under mild conditions by treatment with magnesium bromide in ether at room temperature.
Anodic Oxidation of O-Benzoylated α-Hydroxyacetic Acids - A Contribution to the Reactivity of Anodic Oxidated Carboxylate Ions - "Umpolung"
Thomas, H. Guenter,Kessel, Stephan
, p. 2777 - 2788 (2007/10/02)
Anodic oxidation of O-benzoylated α-hydroxyacetic acid 1 at graphite electrodes in methanol leads to the corresponding mixed acylals 2 and methyl benzoates 3.The rate 2:3 depends on the substitution of the aromatic ring and can be correlated to Hammett's ?-values.
