98508-70-4Relevant academic research and scientific papers
Desulfurization of Diaryl(heteroaryl) Sulfoxides with Benzyne
Chen, De-Li,Sun, Yan,Chen, Mengyuan,Li, Xiaojin,Zhang, Lei,Huang, Xin,Bai, Yihui,Luo, Fang,Peng, Bo
supporting information, (2019/06/13)
Two benzyne-enabled desulfurization reactions have been demonstrated which convert diaryl sulfoxides and heteroaryl sulfoxides to biaryls and desulfurized heteroarenes, respectively. The reaction accessing biaryls tolerates a variety of functional groups, such as halides, pseudohalides, and carbonyls. Mechanistic studies reveal that both reactions proceed via a common assembly process but divergent disassemblies of the generated tetraaryl(heteroaryl) sulfuranes.
1,2,3-trisubstituted indoles for treatment of inflammation
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, (2008/06/13)
Disclosed are compounds of the formula STR1 wherein the several groups are defined herein. These compounds are useful for treating inflammation.
A NOVEL SYNTHESIS OF 3-CYANOINDOLES AND A NEW ROUTE TO INDOLE-3-CARBOXYLIC ACID DERIVATIVES.
Garcia, Josefina,Greenhouse, Robert,Muchowski, Joseph M.,Ruiz, Jose Antonio
, p. 1827 - 1830 (2007/10/02)
2-Alkyl-3-cyanoindoles are obtained when 1-alkylmethyl-2-chloro-(or 2-phenylsulfonyl)-3-phenylsulfonylindoles are reacted with excess azide ion (90 deg C/DMF).The reaction is considered to occur by a fragmentation recombination process in which the Schiff
