98749-91-8

Basic information

• Product Name: Phenyl-1 trimethyl-1,3,4 silole
• Synonyms: Phenyl-1 trimethyl-1,3,4 silole
• CAS NO: 98749-91-8
• Molecular Weight: 200.356
• Mol File: 98749-91-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Phenyl-1 trimethyl-1,3,4 silole(CAS DataBase Reference)
• NIST Chemistry Reference: Phenyl-1 trimethyl-1,3,4 silole(98749-91-8)
• EPA Substance Registry System: Phenyl-1 trimethyl-1,3,4 silole(98749-91-8)

Safety Data

• Hazardous Substances Data: 98749-91-8(Hazardous Substances Data)

Upstream product

• 82763-95-9 tetramethyl-1,1,3,4 silole 
• 591-51-5 phenyllithium 

Downstream Products

• 118760-20-6 (C₄H₂(CH₃)2Si(CH₃)C₆H₅)Fe(CO)3 
• 129176-24-5 {Rh(η4-Me2C4H2SiMePh)(PPh3)2}(SbF6) 
• 129176-24-5 {Rh(η4-Me2C4H2SiMePh)(PPh3)2}(BF4) 
• 129176-24-5 {Rh(η4-Me2C4H2SiMePh)(PPh3)2}(PF6) 

Relevant articles and documents

CHIMIE DES METALLOLES IV B . ACTION D'ORGANOLITHIENS SUR LES TETRAMETHYL-1,1,3,4 SILOLE OU GERMOLE

The reaction of RLi ( R=nBu,tBu,PhLi ) with 1,1,3,4-tetramethylsilole or germole in THF gives via a ligand exchange ( SN-Si or Ge ) the 1-R-1,3,4 trimethylmetalloles or the 1,1-di-R-3,4-dimethylmetalloles (A).Metalation of MMe groups is not observed but a partial (nBuLi,PhLi) or important (tBuLi) isomerization of metalloles into the transoid exocyclic dienes (B) occurs.