Tetrahedron Letters p. 1315 - 1318 (1985)
Update date:2022-08-04
Topics:
Dubac, Jacques
Iloughmane, Hafida
Laporterie, Andre
Roques, Christian
The reaction of RLi ( R=nBu,tBu,PhLi ) with 1,1,3,4-tetramethylsilole or germole in THF gives via a ligand exchange ( SN-Si or Ge ) the 1-R-1,3,4 trimethylmetalloles or the 1,1-di-R-3,4-dimethylmetalloles (A).Metalation of MMe groups is not observed but a partial (nBuLi,PhLi) or important (tBuLi) isomerization of metalloles into the transoid exocyclic dienes (B) occurs.
View MoreContact:86-10-62983737; +86-10-51287608
Address:4/F Building C, 2 Shangdi Xinxi Road
Contact:86-898-65311214
Address:Room 102, BLDG. 68 Jiangnan City, No. 66 Heping Road,Haikou, Hainan, China
Contact:+86-25-83719363
Address:106-7 Chunnan Rd, Chunxi Town, Gaochun, Nanjing, China
website:http://www.shochem.com
Contact:021-50800795
Address:No.1043, Halei Rd, Zhangjiang Hi-Tech Park, Shanghai, Postcode 201203, China
Anhui Xinyuan Technology Co.,Ltd
Contact:0086-559-3515800
Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Doi:10.1021/ac990139w
(1999)Doi:10.1007/s00044-015-1477-7
(2016)Doi:10.1016/j.tetlet.2021.153252
(2021)Doi:10.1021/ja01577a047
(1957)Doi:10.1016/S0040-4039(00)98614-3
(1985)Doi:10.1246/bcsj.58.2943
(1985)
