98750-72-2Relevant academic research and scientific papers
Additive Pummerer Rearrangements. Asymmetric Synthesis of (-)-Methyl Jasmonate
Posner, Gary H.,Asirvatham, Edward,Ali, Syed F.
, p. 542 - 543 (1985)
Examples of mild, additive Pummerer rearrangements are given; one example involves asymmetric carbon-carbon bond formation as the key step for synthesis of (-)-methyl jasmonate.
THE REACTION OF ALKYL PHENYL SULPHIDES WITH MANGANESE DIOXIDE AND ACETYL CHLORIDE
Bellesia, Franco,Ghelfi, Franco,Pagnoni, Ugo Maria,Pinetti, Adriano
, p. 289 - 291 (2007/10/02)
In a one-pot reaction, manganese dioxide in stoichiometric amounts and acetyl chloride transform alkyl phenyl sulphides into the corresponding 1-alkenyl phenyl sulphides; these latter products can be undergo chlorination of the double bond promoted by the
