13910-16-2Relevant articles and documents
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Molinari,H. et al.
, p. 3920 - 3927 (1979)
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Triphenylsulfonium Salts as Effective Phase Transfer Catalysts under Alkaline Conditions
Kondo, Shuji,Takeda, Yuji,Tsuda, Kazuichi
, p. 862 - 864 (1989)
Triphenylsulfonium salts work as effective phase transfer catalysts for nucleophilic substitution reactions on alkyl halides (e.g. 1) and addition reaction of dichlorocarbene to cyclohexene (8) under strongly alkaline conditions.
Convenient Synthesis of Organic Sulfides Using Impregnated Reagents
Czech, Bronislaw,Quici, Silvio,Regen, Steven L.
, p. 113 (1980)
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Facile Thiol–Ene Click Protocol Using Benzil as Sensitizer and White LED as Light Source
Das, Anupam,Thomas, K. R. Justin
supporting information, p. 7214 - 7218 (2020/11/30)
The thiol–ene reaction leading to a series of thioether derivatives by simple metal and oxidant free visible light promoted photosensitized protocol, following anti-Markonikov hydrothiolation of unactivated aryl and alkyl olefins at room temperature is demonstrated. Benzil served as a green photosensitizer in this reaction and white LED lights as a light source. This radical based thiol–ene reaction is operationally simple and tolerates a wide variety of functional groups present in olefins.
Nickel-Catalyzed Inter- and Intramolecular Aryl Thioether Metathesis by Reversible Arylation
Delcaillau, Tristan,Bismuto, Alessandro,Lian, Zhong,Morandi, Bill
supporting information, p. 2110 - 2114 (2019/12/24)
A nickel-catalyzed aryl thioether metathesis has been developed to access high-value thioethers. 1,2-Bis(dicyclohexylphosphino)ethane (dcype) is essential to promote this highly functional-group-tolerant reaction. Furthermore, synthetically challenging macrocycles could be obtained in good yield in an unusual example of ring-closing metathesis that does not involve alkene bonds. In-depth organometallic studies support a reversible Ni0/NiII pathway to product formation. Overall, this work not only provides a more sustainable alternative to previous catalytic systems based on Pd, but also presents new applications and mechanistic information that are highly relevant to the further development and application of unusual single-bond metathesis reactions.