98793-56-7

Upstream product

• 71722-30-0 1-hydroxy-1-phenyl-2-phenylthiopent-2-ene 
• 71722-29-7 1-phenyl-3-phenylsulphinyl-2-phenylthiopent-1-ene 
• 1009-14-9 phenyl butyl ketone 
• 49851-31-2 α-bromovalerophenone 
• 59919-12-9 1-Phenyl-2-phenylthiopentan-1-one 
• 71722-19-5 1-phenyl-2,3-bisphenylthiopent-1-ene 
• 69063-50-9 1-phenyl-2,2-bisphenylthiopentan-3-ol 
• 54905-12-3 (2-phenylethane-1,1-diyl)bis(phenylsulfane) 
• 108-98-5 thiophenol 
• 852524-43-7 acetic acid 2-diazo-1-ethyl-3-oxo-3-phenyl-propyl ester 
• 95607-26-4 1-phenyl-2-phenylsulphinylpentan-1-one 

Relevant academic research and scientific papers

1,2-Thio group migration in Rh(II) carbene reactions

A series of β-thio group substituted α-diazo carbonyl compounds have been prepared by nucleophilic substitution reactions of thiophenol, thionaphthol, or benzyl mercaptan with β-acetoxy-α-diazo carbonyl compounds. The diazo decomposition of these diazo ca

Synthesis of α-Phenylthio Enones and Esters of α-Phenylthio Alkenoic Acids

The title compounds can be made by a Pummerer dehydration from the corresponding saturated sulphoxides.The alkylation of anions from saturated and unsaturated ketones is described.

Phenylthio Migrations in Rearrangements of 2,2-Bisphenylthioethanols

Thionyl chloride causes rearrangement of the title compounds to give 2,3-bisphenylthiopropenes (12) by a phenylthio shift.The products undergo phenylthio shifts on exposure to light.Some applications to synthesis are described.