98796-23-7Relevant academic research and scientific papers
Short syntheses of 1-substituted dibenzothiophene derivatives
Welsh, Erin N.,Robertson, Katherine N.,Speed, Alexander W. H.
, p. 2000 - 2007 (2021/03/16)
The 1-substituted dibenzothiophene motif is an unusual substitution pattern that has previously been accessedviaa multi-step synthesis. We demonstrate a simple one-pot preparation of 1-lithiodibenzothiophene from commercial materialsviaa cascade of two benzyne additions and conversion to several derivatives by addition of electrophiles. A chiral amine containing the 1-dibenzothiophene motif was also prepared. This work avoids the use of precious metals ortert-butyllithium and is much shorter and more convenient than existing routes to 1-substituted dibenzothiophenes.
Compound Containing At Least Two 5-Membered Heterocycle And Organic Electronic Element Using The Same, Terminal Thereof
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Paragraph 0098-0100, (2016/11/09)
The present invention refers to 2 has a compound having a heterocyclic user one or more five won and electrical component, provides terminal with.
A route to regioselectively functionalized carbazoles, dibenzofurans, and dibenzothiophenes through anionic cyclization of benzyne-tethered aryllithiums
Sanz, Roberto,Fernandez, Yolanda,Castroviejo, Ma. Pilar,Perez, Antonio,Fananas, Francisco J.
, p. 6291 - 6294 (2007/10/03)
The treatment of 2-fluorophenyl 2-iodophenylamines, ether, and thioether, easily prepared from commercially available products, with 3.3 equiv of t-BuLi and further reaction with selected electrophiles gives rise to functionalized carbazole, dibenzofuran, and dibenzothiophene derivatives in a direct and regioselective manner. The process involves an anionic cyclization on a benzyne-tethered aryllithium intermediate.
