98944-52-6Relevant academic research and scientific papers
Almond oxynitrilase-catalyzed transformation of aldehydes is strongly influenced by naphthyl and alkoxy substituents
Roda, Gabriella,Riva, Sergio,Danieli, Bruno
, p. 3939 - 3949 (2007/10/03)
Different α- and β-substituted aldehydes have been submitted to the catalytic action of almond oxynitrilase (PaHNL), in order to explore the influence of a stereocenter already present in the substrate on the selectivity of this enzyme. The results indicate that naphthyl and alkoxy substituents in the α- and also in the β-position to the aldehyde group significantly influence the stereochemical outcome of the PaHNL-catalyzed transformation.
Unique Stereocontrol in Europium (III)-Catalyzed Cyanosilylation of chiral α-Alkoxy and α-Amino Aldehydes
Gu, Jin-Hua,Okamoto, Mikako,Terada, Masahiro,Mikami, Koichi,Nakai, Takeshi
, p. 1169 - 1172 (2007/10/02)
The Eu(III)-catalyzed cyanosilylations of chiral α-alkoxy and α-amino aldehydes are shown to exhibit syn diastereofacial selection, the degree increasing with an increase in steric bulk of the alkyl chain in the aldehydes.The mechanism of this catalytic p
