99060-14-7

Basic information

• Product Name: Formamide, N-[2-(4-methylphenyl)-2-oxoethyl]-
• CAS NO: 99060-14-7
• Molecular Formula: C10H11NO2
• Molecular Weight: 177.203
• Mol File: 99060-14-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Formamide, N-[2-(4-methylphenyl)-2-oxoethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Formamide, N-[2-(4-methylphenyl)-2-oxoethyl]-(99060-14-7)
• EPA Substance Registry System: Formamide, N-[2-(4-methylphenyl)-2-oxoethyl]-(99060-14-7)

Safety Data

• Hazardous Substances Data: 99060-14-7(Hazardous Substances Data)

Upstream product

• 64-18-6 formic acid 
• 32687-33-5 3-p-tolyl-2H-azirine 
• 619-41-0 4-(bromoacetyl)toluene 
• 127118-89-2 C₁₁H₁₁NO₃ 

Downstream Products

• 87087-20-5 isoquinoline-7-carboxaldehyde 
• 54004-38-5 7-methyl isoquinoline 
• 102014-89-1 formic acid-(β-hydroxy-4-methyl-phenethylamide) 

Relevant articles and documents

Self-Catalyzed Rapid Synthesis of N-Acylated/ N-Formylated α-Aminoketones and N-Hydroxymethylated Formamides from 3-Aryl-2 H-Azirines and 2-Me/Ph-3-Aryl-2 H-Azirines

A rapid and effective method has been established for the synthesis of N-acylated α-aminoketone derivatives by the reaction of 3-aryl-2H-azirines and highly substituted 2-Me/Ph-3-aryl-2H-azirines with various carboxylic acids under ambient air within 10 min at room temperature. N-Trifluoroacetylated α-aminoketones with different substituents have been reported in the presence of trifluoroacetic acid. This protocol is equally effective to synthesize N-formylated α-aminoketone and N-hydroxymethylated formamide derivatives.

A CONVENIENT PREPARATION OF AMINOMETHYL ARYL KETONES AND THEIR DERIVATIVES

A convenient preparation of N-phenacyl diformamides, N-phenacyl formamides and aminomethyl aryl ketone hydrochlorides from aryl bromomethyl ketones and sodium diformylamide was described.