99129-11-0Relevant academic research and scientific papers
A semiconducting supramolecular Co(ii)-metallohydrogel: an efficient catalyst for single-pot aryl-S bond formation at room temperature
Dhibar, Subhendu,Dey, Amiya,Jana, Rajkumar,Chatterjee, Arpita,Das, Gourab Kanti,Ray, Partha Pratim,Dey, Biswajit
supporting information, p. 17388 - 17394 (2019/12/02)
A novel mechanically stable supramolecular Co(ii)-metallohydrogel has been synthesized. Cobalt(ii) nitrate hexahydrate and monoethanolamine, as a low molecular weight organic gelator, are used to get the gel. The mechanical stability of the supramolecular hydrogel was analyzed. The morphology of the supramolecular metallohydrogel was scrutinized. The semiconducting features of the metallohydrogel were studied. The conducting properties of the Co(ii)-metallohydrogel establish a Schottky barrier diode type nature. The catalytic nature of the Co(ii)-metallohydrogel based room temperature single pot aryl-S coupling reaction was explored. Most interestingly, the Co(ii)-metallohydrogel based catalytic aryl-S coupling reaction does not require any column-chromatographic purification protocol to get pure aryl-thioethers. Thus, through this work a semiconducting Schottky barrier diode application and catalytic role in the room temperature single pot aryl-S coupling reaction of a supramolecular Co(ii)-metallohydrogel have been explored.
SNAr Reaction of 1,5-Dichloro-2,4-dinitrobenzene with S-, O-, and N-Nucleophiles
Begunov,Gopanyuk,Sokolov,Sakulina
, p. 945 - 948 (2018/07/31)
A simple and convenient procedure has been proposed for the synthesis of 1,3,4-tris(4-R-phenylsulfanyl)- 6-nitrobenzene and 1,3,4,6-tetrakis(4-R-phenylsulfanyl)benzene by reaction of 1,5-dichloro-2,4-dinitrobenzene with various benzenethiols.
Synthesis of Di-, Tri-, and tetrasulfides through multifold carbon-sulfur cross-coupling reactions with indium tri(organothiolates) in a one-pot procedure
Lee, Phil Ho,Park, Youngchul,Park, Sangkyun,Lee, Euijae,Kim, Sunggak
scheme or table, p. 760 - 765 (2011/04/15)
Pd-catalyzed multifold (2-, 3-, and 4-fold) carbon-sulfur cross-coupling reaction of indium tri(organothiolates) with polybromonated aromatic and heteroaromatic compounds was developed in a one-pot procedure. Both 2,5-dibromopyridine and 2,6-dibromopyridi
Substitution of Unactivated Aryl Halides by Thiolate Anions in Polyglymes
Pastor, Stephen D.,Hessell, Edward T.
, p. 4812 - 4815 (2007/10/02)
Tetraglyme was found to be a suitable reaction medium to effect the substitution of hexa-, tetra-, tri-, di-, and monochlorobenzenes with sodium alkanethiolates.The substitution of hexa-, tetra-, and trichlorobenzenes by sodium benzenethiolate gave the co
