99166-43-5Relevant academic research and scientific papers
A Stereoselective Totally Synthetic Route to Methyl α-Peracetylhikosaminide
Danishefsky, Samuel J.,Maring, Clarence J.
, p. 2193 - 2204 (2007/10/02)
A synthesis of the title system from D-galactose has been achieved.The racemic galactose 1,2,3,4-bisacetonide is expanded to a C7 heptulose, which is then extended to an undecose by a Lewis acid catalyzed cyclocondensation reaction.Racemic galactose was s
ON THE COMMUNICATION OF CHIRALITY FROM FURANOSE AND PYRANOSE RINGS TO MONOSACCHARIDE SIDE CHAINS: ANOMALOUS RESULTS IN THE GLUCOSE SERIES
Danishefsky, Samuel J.,DeNinno, Michael P.,Phillips, Gary B.,Zelle, Robert E.
, p. 2809 - 2819 (2007/10/02)
The reactions of allyltrimethylsilane with dialdose derivatives occur, under catalysis by boron trifluoride etherate or titanium tetrachloride, with high stereoselectivity, thereby providing simple routes to the corresponding allyl carbinols.The sense of
