99224-30-3

Basic information

• Product Name: ethyl 3-((2-bromophenyl)(methyl)amino)-3-oxopropanoate
• Synonyms: ethyl 3-((2-bromophenyl)(methyl)amino)-3-oxopropanoate
• CAS NO: 99224-30-3
• Molecular Weight: 300.152
• Mol File: 99224-30-3.mol

Chemical Properties

• CAS DataBase Reference: ethyl 3-((2-bromophenyl)(methyl)amino)-3-oxopropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 3-((2-bromophenyl)(methyl)amino)-3-oxopropanoate(99224-30-3)
• EPA Substance Registry System: ethyl 3-((2-bromophenyl)(methyl)amino)-3-oxopropanoate(99224-30-3)

Safety Data

• Hazardous Substances Data: 99224-30-3(Hazardous Substances Data)

Upstream product

• 615-36-1 2-bromoaniline 
• 6832-87-7 2-bromo-N-methylaniline 
• 36239-09-5 ethyl chlorocarbonylacetate 

Downstream Products

• 1373442-87-5 ethyl 3-((2-bromophenyl)(methyl)amino)-2-hydroxy-3-oxopropanoate 

Relevant articles and documents

Asymmetric construction of quaternary α-nitro amides by palladium-catalyzed C(sp3)-H arylation

Pd-Catalyzed enantioselective C(sp3)-H arylation of N-(o-Br-aryl) anilides has been disclosed, and quaternary α-nitro amides were constructed with up to 98% ee. The presence of the nitro group on the substrate enables the progress of the reaction and the ready transformation of the product to optically active quaternary amino acid derivatives.