99307-43-4Relevant academic research and scientific papers
A novel 3D terbium metal-organic framework as a heterogeneous Lewis acid catalyst for the cyanosilylation of aldehyde
Duan, Chunying,He, Cheng,Liu, Yuqian,Zhao, Peiran
, p. 34779 - 34787 (2021/12/02)
A novel 3D lanthanide(iii) metal-organic framework (MOF) (namely Tb-MOF), was synthesized by self-assembly from Tb(iii) ion nitrate and the rigid organic ligand H2sbdc (H2sbdc = 5,5-dioxo-5H-dibenzo[b,d]thiophene-3,7-dicarboxylic acid), and could work as
PhI(OAc)2-mediated alkoxyoxygenation of β,γ-unsaturated ketoximes: Preparation of isoxazolines bearing two contiguous tetrasubstituted carbons
Ye, Chenghao,Kou, Xuezhen,Yang, Guoqiang,Shen, Jiefeng,Zhang, Wanbin
supporting information, p. 1148 - 1152 (2019/03/26)
A PhI(OAc)2-promoted dioxygenation of allyl oximes, including one alkoxylation, has been developed. This reaction can give isoxazoline products bearing two contiguous tetrasubstituted carbons. Various oximes substrates bearing different aryl groups and tetrasubstituted-olefin moieties were compatible with the mild reaction conditions. A two-electron oxidation pathway was proposed based on results of preliminary mechanistic studies.
A dual-functional Cd(II)-organic-framework demonstrating selective sensing of Zn2+ and Fe3+ ions exclusively and size-selective catalysis towards cyanosilylation
Zhang, Xiao-Nan,Liu, Lin,Han, Zheng-Bo,Gao, Ming-Liang,Yuan, Da-Qiang
, p. 10119 - 10124 (2015/02/05)
A dual-functional complex with the formula Cd2(L)(DMF)2(H2O)2 (L = 2,3′,5,5′-biphenyl tetracarboxylic acid) has been successfully synthesized under solvothermal conditions and characterized by thermogravimetric
Robust molecular bowl-based metal-organic frameworks with open metal sites: Size modulation to increase the catalytic activity
Liu, Lin,Han, Zheng-Bo,Wang, Shi-Ming,Yuan, Da-Qiang,Ng, Seik Weng
supporting information, p. 3719 - 3721 (2015/05/04)
Herein, two stable lead(II) molecular-bowl-based metal-organic frameworks and their micro- and nanosized forms with open metal sites were presented. These materials could act as Lewis acid catalysts to cyanosilylation reaction. Moreover, the catalytic per
4,5-Dihydropyridazin-3-one derivatives as histamine H3 receptor inverse agonists
Hudkins, Robert L.,Aimone, Lisa D.,Dandu, Reddeppa Reddy,Dunn, Derek,Gruner, John A.,Huang, Zeqi,Josef, Kurt A.,Lyons, Jacquelyn A.,Mathiasen, Joanne R.,Tao, Ming,Zulli, Allison L.,Raddatz, Rita
scheme or table, p. 194 - 198 (2012/03/10)
H3R structure-activity relationships for a new class of 4,5-dihydropyridazin-3-one H3R antagonists/inverse agonists are disclosed. Modification of the 4,5-dihydropyridazinone moiety to block in vivo metabolism identified 4,4-dimethyl
Montmorillonite-K10 catalyzed addition of trimethylsilylcyanide (TMSCN) to aldehydes
Somanathan,Rivero,Gama, Angeles,Ochoa,Aguirre
, p. 2043 - 2048 (2007/10/03)
Addition of trimethylsilyl cyanide (TMSCN) to aldehydes was catalyzed by Montmorillonite-K10, with subsequent reduction to β-aminoalcohol.
Enzymatic Preparation of Optically Active Cyanohydrin Acetates
Almsick, Andreas van,Buddrus, Joachim,Hoenicke-Schmidt, Petra,Laumen, Kurt,Schneider, Manfred P.
, p. 1391 - 1393 (2007/10/02)
A series of cyanohydrin acetates (1)-(47) of widely varying structures, potential chiral building blocks for numerous synthetic applications, has been prepared in good chemical and often high optical yields by enzymatic hydrolysis of their racemic acetates in the presence of an ester hydrolase from Pseudomonas sp.
