99388-26-8Relevant academic research and scientific papers
Glycosylation employing glycopyranosyl fluorides promoted by TiF4 under mild conditions
Thiem, Joachim,Wiesner, Matthias
, p. 398 - 414 (2020/11/12)
Glycopyranosyl fluorides are shown as efficient glycosyl donors by glycosylation of appropriate aglycon structures under mild conditions with Lewis acid catalysis in anhydrous ether or acetonitrile. Further direct reaction sequences gave naturally occurri
Regioselective removal of the anomeric O-benzyl from differentially protected carbohydrates
Jalsa, Nigel Kevin
, p. 6587 - 6590 (2012/02/03)
A mild, regioselective deprotection of the anomeric O-benzyl from multi-functionally protected carbohydrates via catalytic transfer hydrogenation is described. The protocol is tolerant of O-benzyl and O-benzylidene protections at non-anomeric positions, g
On the synthesis of vinyl and phenyl C-furanosides by stereospecific debenzylative cycloetherification
Cribiù, Riccardo,Eszter Borbas,Cumpstey, Ian
experimental part, p. 2022 - 2031 (2009/07/18)
Open-chain benzyl-ether-protected polyols in which one of the alcohols is either allylic or benzylic are synthesised by addition of organometallic vinyl or phenyl reagents to benzyl-ether-protected carbohydrate hemiacetals. The diastereoselectivity of add
An extremely mild and general method for the stereocontrolled construction of 1,2-cis-glycosidic linkages via S-glycopyranosyl phosphorodiamidimidothioates
Hashimoto, Shun-Ichi,Honda, Takeshi,Ikegami, Shiro
, p. 4769 - 4772 (2007/10/02)
A highly stereocontrolled construction of 1,2-cis-glycosidic linkages under extremely mild reaction conditions has been developed by using S-glycopyranosyl N,N,N′,N′-tetramethyl-N-phenylphosphorodiamidimidothioates with a non-participating O-2-benzyl grou
A Rapid and Efficient Synthesis of 1,2-trans-β-Linked Glycosides via Benzyl- or Benzoyl-protected Glycopyranosyl Phosphates
Hashimoto, Shun-ichi,Honda, Takeshi,Ikegami, Shiro
, p. 685 - 687 (2007/10/02)
A highly stereocontrolled construction of 1,2-trans-β-glycosidic linkage with or without neighbouring-group participation has been achieved using benzyl- or benzoyl-protected glycopyranosyl phosphates as glycosyl donors in the presence of trimethylsilyl t
4-O-beta-D-Galactopyranosyl-3-O-methyl-D-glucose: a new synthesis and application to the evaluation of intestinal lactase.
Fernandez-Mayoralas,Martin-Lomas,Villanueva
, p. 81 - 91 (2007/10/02)
4-O-beta-D-Galactopyranosyl-3-O-methyl-D-glucose (1, 3-O-methyl-lactose) has been prepared from benzyl 2,6-di-O-benzyl-4-O-(2,6-di-O-benzyl-3, 4-O-isopropylidene-beta-D-galactopyranosyl)-beta-D-glucopyranoside (5) and from benzyl 2,6-di-O-benzyl-4-O-(2,3,
