99414-73-0Relevant academic research and scientific papers
Towards allopumiliotoxins: A concise synthesis of the indolizidine core
Vijaykumar, Bodduri V. D.,Mallesham, Pitchakuntla,Chandrasekhar, Srivari
experimental part, p. 988 - 994 (2012/04/04)
The common bicyclic indolizidine core present in several allopumiliotoxins was synthesized by the sequential use of a Crimmins' aldol reaction, an SOCl2-mediated SNi displacement, and an intramolecular nucleophilic acyl substitution (INAS) as the key transformations. A concise synthesis of the indolizidine core of allopumiliotoxins is described by using an aldol reaction, an SNi displacement and an intramolecular nucleophilic acyl substitution as key steps. Copyright
