99417-11-5

Upstream product

• 63469-50-1 2-<1-(6-methoxynaphthyl)>ethanol 
• 98-09-9 benzenesulfonyl chloride 
• 1078-19-9 6-methoxy-3,4-dihydro-1(2H)-naphthalenone 
• 40154-02-7 2-(6-methoxy-3,4-dihydro-naphthalen-1-yl)-acetic acid ethyl ester 
• 99416-98-5 Ethyl 2-<1-(6-methoxynaphthyl)>acetate 

Downstream Products

• 99417-01-3 3-<2-(6-methoxy-1-naphthyl)ethyl>-2-cyclohexeneone 

Relevant academic research and scientific papers

Methoxybenzopyrene 4,5-Oxides Labeled with Carbon-13: Electronic Effects in the NIH Shift

The synthesis of 9-methoxy-4,5-dihydrobenzopyrene-4-13C4,5-oxide and -5-13C4,5-oxide and of 8-methoxy-4,5-dihydrobenzopyrene-4-13C4,5-oxide is reported.The compounds were synthesized in yields of 15percent each from unlabeled precursors. 13C NMR analysis of the conversion of the 4,5-oxides to 4-phenols and 5-phenols (NIH shift) revealed a very strong electronic effect of a 9-methoxy substituent, which gave only the 4-phenol, and a significant but weaker effect of an 8-methoxy substituent, which gave both phenols with the 5-phenol predominating.