99512-23-9Relevant academic research and scientific papers
Ir-catalysed formation of C-F bonds. From allylic alcohols to α-fluoroketones
Ahlsten, Nanna,Martin-Matute, Belen
, p. 8331 - 8333 (2011)
A novel iridium-catalysed tandem isomerisation/C-F bond formation from allylic alcohols and Selectfluor to prepare α-fluorinated ketones as single constitutional isomers is reported.
Asymmetric 1,2-reduction of enones with potassium borohydride catalyzed by chiral N,N′-dioxide-scandium(III) complexes
He, Peng,Liu, Xiaohua,Zheng, Haifeng,Li, Wei,Lin, Lili,Feng, Xiaoming
supporting information, p. 5134 - 5137,4 (2020/09/15)
The first catalytic enantioselective 1,2-reduction of enones with 0.45 mol equiv potassium borohydride solution catalyzed by a chiral N,N′-dioxide- Sc(III) complex catalyst was accomplished under mild reaction conditions. A number of optically active allylic alcohols were obtained in good to excellent enantioselectivities (up to 95% ee) with nearly quantitative yields.
