99630-91-8

Upstream product

• 75-44-5 phosgene 
• 79-37-8 oxalyl dichloride 
• 7291-22-7 perdeuteriopyridine 
• 99595-45-6 W(CC₆H₅)Cl(CO)(C₄H₂O₃)(C₅H₅N)2 

Downstream Products

• 99595-38-7 N(C₂H₅)4⁽¹⁺⁾*W(CC₆H₅)Cl₂(CO)(C₄H₂O₃)(C₅H₅N)^(1-) = (N(C₂H₅)4)(W(CC₆H₅)Cl₂(CO)(C₄H₂O₃)(C₅H₅N)) 
• 99595-45-6 W(CC₆H₅)Cl(CO)(C₄H₂O₃)(C₅H₅N)2 
• 105501-08-4 ((C₃H₃N₂)3HB)(CO)2WCC₆H₅ 
• 212509-36-9 ClW(.tplbond.CPh)(CO)2(η(2)-tris(2-pyridyl)phosphine) 
• 99595-34-3 (N(P(C₆H₅)3)2)⁽¹⁺⁾*W(CC₆H₅)Cl₂(CO)2(C₅H₅N)^(1-) = (N(P(C₆H₅)3)2)(W(CC₆H₅)Cl₂(CO)2(C₅H₅N)) 
• 212509-42-7 [W(.tplbond.CPh)(CO)2(η(3)-tris(2-pyridyl)methane)]BPh4 
• 108452-78-4 (CH₃CH₂)4N⁽¹⁺⁾*W((C₆H₅)CCO)((C₄H₃N)CHNCH₃)2(CO)^(1-) = [(CH₃CH₂)4N][W((C₆H₅)CCO)((C₄H₃N)CHNCH₃)2(CO)] 

Relevant academic research and scientific papers

Synthesis of (carbyne)metal complexes by oxide abstraction from acyl ligands

Stable carbyne complexes of the type trans-X(CO)2L2M≡CR (M = Cr, Mo, W; R = C6H5, CH3; X = Cl, Br, CF3C(O)O, L2 = 2 pyridine, tetramethylethylenediamine) are prepared in a single synthesis step by reaction of the respective acyl complexes [NMe4] [(CO)5MC(O)R] at low temperatures with COCl2, C2O2Cl2, CIC(O)OCCl3, C2O2Br2, or (CF3CO)2O and subsequent addition of the nitrogenous ligands at warmer temperatures.

Formation and characterization of stable alkylidyne(alkene)tungsten complexes

Reaction of the alkylidyne complexes [W(CPh)Cl(CO)2(Py)2], [Kat][W(CR)Cl2(CO)2(py)], and [W-(CPh)Cl(CO)2(tmeda)] with maleic anhydride and fumaronitrile results in substitution of carbon monoxide and

Synthesis and substitution reactions of tris- and tetrakis(trimethyl phosphite)-substituted carbyne complexes of chromium, molybdenum, and tungsten

Methods for the synthesis of X(CO)[P-(OMe)3]3M≡CPh (M = Cr, X = Br; M = Mo, W, X = Cl) and Cl[P(OMe3)]4M≡CPh (M = Mo, W) starting from the acyl complexes [NMe4] [(CO)5M-C(O)Ph] are described. Substitution of two or all four trimethyl phosphite ligands in Cl[P(OMe)3]4W=CPh by bis(diphenylphosphino)ethane is demonstrated. The crystal structure of Cl[P-(OMe)3]4Mo≡CPh is reported.