Cationic Rhodium(I) Complexes of 1,4,8,11-Tetrathiacyclotetradecane (aneS4) and the 6,6,13,13-Tetramethyl Analogue (Me4aneS4). Preparation of Two Conformers, X-Ray Crystal Structure of (RhaneS4))2Cl2*MeCN, and Conformational Effect on the Nucleophilicity of the Rhodium(I) Ion

DOI: 10.1039/c39850001137

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1137 - 1138 (1985)

Update date:2022-07-29

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Authors:

Yoshida, Toshikatsu

Ueda, Tatsuo

Adachi, Tomohiro

Yamamoto, Kazuhiko

Higuchi, Taiichi

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Article abstract of DOI:10.1039/c39850001137

Two conformers for the cationic rhodium(I) complexes of the title 14-membered cyclic tetrasulphides have been prepared on the conformational effect upon the nucleophilicity of rhodium(I) ion is shown by the oxidative addition reaction of CH2Cl2; (Rh<14>aneS4)Cl (1), in which the Rh atom lies 0.133(2) Angstroem above the plane of four S atoms, forms a dimer through a Rh...Rh <3.313(1) Angstroem> and four Rh...S <3.697(9)-3.822(3) Angstroem> intermolecular non-bonded interactions as established by an X-ray crystal structure determination.

Full text of DOI:10.1039/c39850001137

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