99683-30-4

Usage

InChI:InChI=1/C10H16O5/c1-3-14-9(12)7-5-6-8(11)10(13)15-4-2/h3-7H2,1-2H3

Upstream product

• 64-17-5 ethanol 
• 611-10-9 2-ethoxycarbonyl-1-cyclopentanone 
• 82415-38-1 ethyl 1-hydroxy-2-oxo-1-cyclopentanecarboxylate 
• 7647-01-0 hydrogenchloride 
• 4755-77-5 Ethyl oxalyl chloride 

Downstream Products

• 250717-23-8 2-[benzyl-(3-nitro-pyridin-2-yl)-hydrazono]-hexanedioic acid diethyl ester 
• 205638-42-2 2-Benzylamino-3-methoxymethoxy-cyclopent-1-enecarboxylic acid ethyl ester 
• 205638-52-4 4-Benzyl-9-ethyl-3-hydroxy-1,2,3,4,6,9-hexahydro-7-oxa-4-aza-cyclopenta[a]naphthalene-5,8-dione 
• 205638-44-4 1-Benzyl-4-hydroxy-7-methoxymethoxy-2-oxo-2,5,6,7-tetrahydro-1H-[1]pyrindine-3-carboxylic acid methyl ester 
• 205638-45-5 1-Benzyl-4-methoxy-7-methoxymethoxy-2-oxo-2,5,6,7-tetrahydro-1H-[1]pyrindine-3-carboxylic acid methyl ester 
• 205638-43-3 2-[Benzyl-(2-methoxycarbonyl-acetyl)-amino]-3-methoxymethoxy-cyclopent-1-enecarboxylic acid ethyl ester 
• 205638-50-2 4-Benzyl-3-methoxymethoxy-5,8-dioxo-1,2,3,4,5,6,8,9-octahydro-7-oxa-4-aza-cyclopenta[a]naphthalene-9-carboxylic acid tert-butyl ester 
• 205638-51-3 4-Benzyl-9-ethyl-3-methoxymethoxy-5,8-dioxo-1,2,3,4,5,6,8,9-octahydro-7-oxa-4-aza-cyclopenta[a]naphthalene-9-carboxylic acid tert-butyl ester 
• 205638-48-8 2-(1-Benzyl-3-formyl-7-methoxymethoxy-2-oxo-2,5,6,7-tetrahydro-1H-[1]pyrindin-4-yl)-malonic acid di-tert-butyl ester 
• 205638-46-6 2-(1-Benzyl-3-methoxycarbonyl-7-methoxymethoxy-2-oxo-2,5,6,7-tetrahydro-1H-[1]pyrindin-4-yl)-malonic acid di-tert-butyl ester 
• 133634-36-3 (-)-(5S)-5-Hydroxy-6-(tolylsulfonyloxy)hexanoate d'ethyle 
• 59812-96-3 (R)-5-hexadecanolide 

Relevant academic research and scientific papers

Expeditious biomimetically-inspired approaches to racemic homocitric acid lactone and per-homocitrate

Two concise and flexible biomimetically-inspired approaches to homocitric acid lactone (3) and its higher homolog, triethyl per-homocitrate (12), are presented herein. The key steps include an efficient indium metal-mediated allylation-oxidative cleavage procedure and a one-step ethoxycarbonylmethylation of α-oxo-diesters.

Highly chemoselective, oxyvanadium-catalysed cleavage of α-hydroxy ketones

α-Hydroxy ketones (α-ketols) can be cleaved chemoselectively with a catalytic amount of dichloroethoxyoxyvanadium under an oxygen atmosphere.

THE FLUORIDE ION EFFECT IN THE REACTIONS OF SINGLET OXYGEN WITH ENOLS

The fluoride ion effect in the reaction of enolic systems with singlet oxygen has been investigated. β-Dicarbonyl compounds yielded 1,2,3-tricarbonyl derivatives, some of which underwent further hydration, whereas α-diketones suffered oxidative decarboxylation to give open-chain aldehydo-acids or keto-acids.