998-62-9Relevant academic research and scientific papers
Rhodium-catalyzed hydroformylation of alkynes employing a self-assembling ligand system
Agabekov, Vladislav,Seiche, Wolfgang,Breit, Bernhard
, p. 2418 - 2422 (2013/07/11)
Hydroformylation of alkynes is an underdeveloped atom-economic and redox-neutral method to prepare enals. Applying a new electron poor self-assembling ligand system provides the first general rhodium-catalyst for the chemo- and stereoselective hydroformylation of dialkyl- as well as diaryl-substituted alkynes to furnish enals in excellent chemo- and stereoselectivity.
Rhodium-katalysierte Hydroformylierung innerer Alkine zu α,β-ungesaettigten Aldehyden
Johnson, John R.,Cuny, Gregory D.,Buchwald, Stephen L.
, p. 1877 - 1879 (2007/10/03)
Keywords: Alkine; Hydroformylierungen; Katalyse; Alkene; Rhodiumverbindungen
Remarkable Effect of the Wavelength in the Photoassisted Carbonylation of the C-H Bond of Decane in the Presence of RhCl(CO)PR3)2 as the Catalyst
Sakakura, Toshiyasu,Sasaki, Koushi,Tokunaga, Yuko,Wada, Keisuke,Tanaka, Masato
, p. 155 - 158 (2007/10/02)
RhCl(CO)(Pr3)2-catalyzed and photoassisted carbonylation of decane leading to the formation of C11 aldehydes and/or 1-nonene was remarkably affected by the wavelength; irradiation with λ > 295 nm was essential to the formation of 1-nonene and undecanal.By cutting off λ 325 nm, 1-nonene formation was completely suppressed, and a series of isomeric C11 aldehydes were obtained.
